Functional models of nonheme diiron enzymes: reactivity of the μ-oxo-μ-1,2-peroxo-diiron(iii) intermediate in electrophilic and nucleophilic reactions

Balázs Kripli, Miklós Szávuly, Flóra Viktória Csendes and József Kaizer

Dalton Trans., 2020, 49, 1742
DOI: 10.1039/C9DT04551A

A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates

Patrik Török, Duenpen Unjaroen, Flóra Viktória Csendes, Michel Giorgi, Wesley R. Browne and József Kaizer

Dalton Trans., 2021, 50, 7181
DOI: 10.1039/D1DT01502H

Hydrogen evolution driven by heteroatoms of bidentate N-heterocyclic ligands in iron(ii) complexes

Soma Keszei, Yiqing Wang, Haotian Zhou, Tamás Ollár, Éva Kováts, Krisztina Frey, Levente Tapasztó, Shaohua Shen and József Sándor Pap

Dalton Trans., 2024, 53, 14817
DOI: 10.1039/D4DT02081B

Functional models of nonheme diiron enzymes: kinetic and computational evidence for the formation of oxoiron(iv) species from peroxo-diiron(iii) complexes, and their reactivity towards phenols and H2O2

Miklós István Szávuly, Mihai Surducan, Emőke Nagy, Mátyás Surányi, Gábor Speier, Radu Silaghi-Dumitrescu and József Kaizer

Dalton Trans., 2016, 45, 14709
DOI: 10.1039/C6DT01598K

A novel coordination mode of κ1-N-Br-pyridylbenz-(imida, oxa or othia)-zole to Pt(ii): synthesis, characterization, electrochemical and structural analysis

Juan Nicasio-Collazo, Gonzalo Ramírez-García, Marcos Flores-Álamo, Silvia Gutiérrez-Granados, Juan M. Peralta-Hernández, José Luis Maldonado, J. Oscar C. Jimenez-Halla and Oracio Serrano

RSC Adv., 2019, 9, 14033
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Microscale coiling in bis-imidazolium supramolecular hydrogel fibres induced by the release of a cationic serine protease inhibitor

David Limón, Claire Jiménez-Newman, Ana C. Calpena, Arántzazu González-Campo, David B. Amabilino and Lluïsa Pérez-García

Chem. Commun., 2017, 53, 4509
DOI: 10.1039/C6CC09392B

Mimicking sMMOH chemistry: trapping the Sc3+-bound nonheme FeIII–O–O–FeIII adduct prior to its conversion into an FeIV2(μ-O)2 core

Patrick M. Crossland, Bittu Chandra, Saikat Banerjee, Chase S. Abelson, Yisong Guo, Marcel Swart and Lawrence Que

Chem. Sci., 2025, 16, 19608
DOI: 10.1039/D5SC05667E

Cobalt(II) and nickel(II) complexes with 1-methyl-2-pyridin-2-yl-1H- and 1-methyl-2-phenyliminomethyl-1H-benzimidazoles and the closo-decaborate anion

V. V. Avdeeva, I. N. Polyakova, L. V. Goeva, E. A. Malinina, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov

Russ. J. Inorg. Chem., 2015, 60, 817
DOI: 10.1134/S0036023615070037

Photoelectrocatalytic Water Splitting by Conformal Copper‐Oxide on Hematite Nanostructures: Dependence on Surface‐States

Tímea Benkó, Shaohua Shen, Miklós Németh, Dávid Lukács, Yufei Xu, Irfan Khan, Zsolt Czigány, Zsolt Endre Horváth, Zoltán Kovács, Jinzhan Su and József Sándor Pap

ChemElectroChem, 2024, 11
DOI: 10.1002/celc.202400191

Catalytic and Stoichiometric Baeyer–Villiger Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates

Dóra Lakk-Bogáth, Miklós István Szávuly, Patrik Török and József Kaizer

Molecules, 2022, 27, 2814
DOI: 10.3390/molecules27092814

Mechanisms of Sulfoxidation and Epoxidation Mediated by Iron(III)-Iodosylbenzene Adduct: Electron-Transfer vs. Oxygen-Transfer Mechanism

Patrik Török, Dóra Lakk-Bogáth and József Kaizer

Molecules, 2023, 28, 4745
DOI: 10.3390/molecules28124745

BiVO4 charge transfer control by a water-insoluble iron complex for solar water oxidation

Tímea Benkó, Shaohua Shen, Miklós Németh, Jinzhan Su, Ákos Szamosvölgyi, Zoltán Kovács, György Sáfrán, Sahir M. Al-Zuraiji, Endre Zsolt Horváth, András Sápi, Zoltán Kónya and József Sándor Pap

Applied Catalysis A: General, 2023, 652, 119035
DOI: 10.1016/j.apcata.2023.119035

Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes

Andrew J. Jasniewski and Lawrence Que

Chem. Rev., 2018, 118, 2554
DOI: 10.1021/acs.chemrev.7b00457

A Mechanistic Study on Iron-Based Styrene Aziridination: Understanding Epoxidation via Nitrene Hydrolysis

Dóra Lakk-Bogáth, Patrik Török, Dénes Pintarics and József Kaizer

Molecules, 2024, 29, 3470
DOI: 10.3390/molecules29153470

Effect of Redox Potential on Diiron-Mediated Disproportionation of Hydrogen Peroxide

Patrik Török, Dóra Lakk-Bogáth and József Kaizer

Molecules, 2023, 28, 2905
DOI: 10.3390/molecules28072905

Utilization of hydrophobic ligands for water-insoluble Fe(II) water oxidation catalysts – Immobilization and characterization

Sahir M. Al-Zuraiji, Tímea Benkó, Levente Illés, Miklós Németh, Krisztina Frey, Attila Sulyok and József S. Pap

Journal of Catalysis, 2020, 381, 615
DOI: 10.1016/j.jcat.2019.12.003

Stoichiometric Aldehyde Deformylation Mediated by Nucleophilic Peroxo‐diiron(III) Complex as a Functional Model of Aldehyde Deformylating Oxygenase

Balázs Kripli, Flóra Viktória Csendes, Patrik Török, Gábor Speier and József Kaizer

Chemistry A European J, 2019, 25, 14290
DOI: 10.1002/chem.201903727

Effect of Substituted Pyridine Co-Ligands and (Diacetoxyiodo)benzene Oxidants on the Fe(III)-OIPh-Mediated Triphenylmethane Hydroxylation Reaction

Patrik Török and József Kaizer

Molecules, 2024, 29, 3842
DOI: 10.3390/molecules29163842

Catalytic oxidation of alcohols and sulfides with hydrogen peroxide using isoindoline and phthalazine-based diiron complexes

Miklós Szávuly, Szilvió D. Szilvási, Róbert Csonka, Dániel Klesitz, Gábor Speier, Michel Giorgi and József Kaizer

Journal of Molecular Catalysis A: Chemical, 2014, 393, 317
DOI: 10.1016/j.molcata.2014.06.030

Disproportionation of H2O2 Mediated by Diiron-Peroxo Complexes as Catalase Mimics

Dóra Lakk-Bogáth, Patrik Török, Flóra Viktória Csendes, Soma Keszei, Beatrix Gantner and József Kaizer

Molecules, 2021, 26, 4501
DOI: 10.3390/molecules26154501

A ligand-centered review on structure, synthesis, and significance of diiron coordination complexes

Aisha Fatima, Nayab Mohsin, Nasir Rasool, Muhammad Imran, Sumera Yasmin and Waseem Nazeer

Journal of Coordination Chemistry, 2025, 78, 2676
DOI: 10.1080/00958972.2025.2605512

Sc3+-Promoted O–O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core

Saikat Banerjee, Apparao Draksharapu, Patrick M. Crossland, Ruixi Fan, Yisong Guo, Marcel Swart and Lawrence Que

J. Am. Chem. Soc., 2020, 142, 4285
DOI: 10.1021/jacs.9b12081

Probing the strong electron-acceptor property of pyridine-appended 1,2,3-benzotriazole ligand in tris-homoleptic Ru(II) and Fe(II) complexes

Sharmila Pandey, Tanmoy Mandal and Sanajit Kumar Mandal

Polyhedron, 2022, 226, 116109
DOI: 10.1016/j.poly.2022.116109

Influence of Equatorial Co-Ligands on the Reactivity of LFeIIIOIPh

Dóra Lakk-Bogáth, Dénes Pintarics, Patrik Török and József Kaizer

Molecules, 2023, 29, 58
DOI: 10.3390/molecules29010058

A growing family of O2 activating dinuclear iron enzymes with key catalytic diiron(III)-peroxo intermediates: Biological systems and chemical models

Alexandre Trehoux, Jean-Pierre Mahy and Frédéric Avenier

Coordination Chemistry Reviews, 2016, 322, 142
DOI: 10.1016/j.ccr.2016.05.014

Effect of monodentate heterocycle co-ligands on the μ-1,2-peroxo-diiron(III) mediated aldehyde deformylation reactions

Patrik Török, Dóra Lakk-Bogáth, Duenpen Unjaroen, Wesley R. Browne and József Kaizer

Journal of Inorganic Biochemistry, 2024, 258, 112620
DOI: 10.1016/j.jinorgbio.2024.112620

An Iron(III) Complex with Pincer Ligand—Catalytic Water Oxidation through Controllable Ligand Exchange

Sahir M. Al-Zuraiji, Dávid Lukács, Miklós Németh, Krisztina Frey, Tímea Benkó, Levente Illés and József S. Pap

Reactions, 2020, 1, 16
DOI: 10.3390/reactions1010003

The effect of nucleophilic cis-coligands on the iron(III)-iodosylbenzene mediated sulfoxidation reactions: Kinetic and DFT study

Mihály Purgel and József Kaizer

Inorganic Chemistry Communications, 2025, 181, 115260
DOI: 10.1016/j.inoche.2025.115260

Formation Pathways of an Electrophilic μ-1,2-Peroxo FeIIIFeIII Complex: Spectroscopic Characterization and Reactivity

Sören Jansen, Fridolin L. B. Röhs, Thomas Philipp Zimmermann, Stephan Walleck, Maurice van Gastel, Ashish Tamhankar, Bufan Zhang, Sergio A. V. Jannuzzi, Ina Kellner, Ivana Ivanović-Burmazović, Serena DeBeer and Thorsten Glaser

J. Am. Chem. Soc., 2026, 148, 7065
DOI: 10.1021/jacs.5c18121

Stoichiometric Alkane and Aldehyde Hydroxylation Reactions Mediated by In Situ Generated Iron(III)-Iodosylbenzene Adduct

Patrik Török, Dóra Lakk-Bogáth and József Kaizer

Molecules, 2023, 28, 1855
DOI: 10.3390/molecules28041855

Kinetic and DFT studies on the iron(III)-iodosylbenzene mediated 9,10-dihydroanthracene oxidation relevance to lipoxygenase enzymes: One or multiple oxidants?

Mihály Purgel, Attila Bényei and József Kaizer

Journal of Molecular Structure, 2026, 1363, 145752
DOI: 10.1016/j.molstruc.2026.145752