A rhodium complex containing tris(o-tert-butyl-p-methylphenyl) phosphite as a ligand catalyses the hydroformylation of oct-1-ene with good selectivity and extremely high rates; the rate constant, which is pseudo first-order in [H2] and 1/[CO], shows that the reaction of hydrogen is the rate determining step.
A. van Rooy, E. N. Orij, P. C. J. Kamer, F. van den Aardweg and P. W. N. M. van Leeuwen, J. Chem. Soc., Chem. Commun., 1991, 1096 DOI: 10.1039/C39910001096
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