Issue 5, 2024

Dual-ion conductors: from liquid to solid

Abstract

The traditional working principle within lithium-ion batteries relies on Li+ shuttling between the cathode and anode, namely the rocking-chair mechanism. A single working ion constrains the possibilities for battery design and the selection of electrode materials, while realizing multiple working ions offers the potential to break through the fundamental principles of traditional battery construction. Accordingly, it is necessary to develop dual-ion conductors to enable the migration of multiple working ions. This focus article starts by introducing traditional dual-ion batteries based on liquid electrolytes and their pros and cons. Then, solidifying liquid dual-ion conductors is expected to overcome these drawbacks, so the development of solid dual-ion conductors is discussed in detail. Specifically, basic design principles of solid dual-ion conductors are briefly proposed, including constructing continuous ion transport channels and choosing appropriately sized ion carriers. The potential applications of solid dual-ion conductors are also summarized, such as stabilizing the electrode/electrolyte interface and activating additional redox couples. The goal of this article is to inspire researchers in the development of dual-ion conductors and to contribute to the advancement of all-solid-state batteries.

Graphical abstract: Dual-ion conductors: from liquid to solid

Article information

Article type
Focus
Submitted
08 янв 2024
Accepted
04 мар 2024
First published
05 мар 2024

Nanoscale Horiz., 2024,9, 667-674

Dual-ion conductors: from liquid to solid

T. Yu, W. Ning, H. Li, S. Guo and H. Zhou, Nanoscale Horiz., 2024, 9, 667 DOI: 10.1039/D4NH00011K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements