Issue 37, 2021

Tuning intermediate adsorption in structurally ordered substituted PdCu3 intermetallic nanoparticles for enhanced ethanol oxidation reaction

Abstract

Co and Ni-substituted structurally ordered intermetallic PdCu3 nanoparticles (NPs) synthesized at low temperature exhibit remarkable enhancement of the ethanol electrooxidation (EOR) activity with improved durability. The first-principle calculations suggest that prompted generation of OH and CH3CO radicals in close proximity and shifting of the d-band center towards the Fermi level boost the EOR efficiency.

Graphical abstract: Tuning intermediate adsorption in structurally ordered substituted PdCu3 intermetallic nanoparticles for enhanced ethanol oxidation reaction

Supplementary files

Article information

Article type
Communication
Submitted
12 дек 2020
Accepted
26 мар 2021
First published
07 апр 2021

Chem. Commun., 2021,57, 4508-4511

Tuning intermediate adsorption in structurally ordered substituted PdCu3 intermetallic nanoparticles for enhanced ethanol oxidation reaction

R. Jana, A. Datta and S. Malik, Chem. Commun., 2021, 57, 4508 DOI: 10.1039/D0CC08075F

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