Issue 94, 2020

Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer

Abstract

Catalytically relevant intermediates in carbene transfer reactions from a diazo precursor were investigated using cobalt corrole complexes. Two divergent mechanisms are proposed depending on the oxidation state of the cobalt center. Mechanistically driven factors for the usage of cobalt corroles in carbene transfer reactions are discussed.

Graphical abstract: Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer

Supplementary files

Article information

Article type
Communication
Submitted
25 окт 2020
Accepted
30 окт 2020
First published
30 окт 2020

Chem. Commun., 2020,56, 14881-14884

Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer

B. W. Musselman and N. Lehnert, Chem. Commun., 2020, 56, 14881 DOI: 10.1039/D0CC07073D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements