Issue 35, 2019

Cation-controlled catalysis with crown ether-containing transition metal complexes

Abstract

Transition metal complexes that incorporate crown ethers into the supporting ligands have emerged as a powerful class of catalysts capable of cation-tunable reactivity. Cations held in the secondary coordination sphere of a transition metal catalyst can pre-organize or activate substrates, induce local electric fields, adjust structural conformations, or even modify bonding in the primary coordination sphere of the transition metal. This Feature Article begins with a non-comprehensive review of the structural motifs and catalytic applications of crown ether-containing transition metal catalysts, then proceeds to detail the development of catalysts based on “pincer-crown ether” ligands that bridge the primary and secondary coordination spheres.

Graphical abstract: Cation-controlled catalysis with crown ether-containing transition metal complexes

Article information

Article type
Feature Article
Submitted
28 янв 2019
Accepted
20 мар 2019
First published
20 мар 2019

Chem. Commun., 2019,55, 5047-5059

Author version available

Cation-controlled catalysis with crown ether-containing transition metal complexes

C. Yoo, H. M. Dodge and A. J. M. Miller, Chem. Commun., 2019, 55, 5047 DOI: 10.1039/C9CC00803A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements