Issue 7, 2023

Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

Abstract

A facile, fast and green strategy based on ethanol is utilized to prepare a new bioMOF, namely, CaSyr-1, with particular characteristics of full biocompatibility given by using just calcium and syringic acid, the latter being a phenolic natural product found in fruits and vegetables, permanent porosity with an outstanding surface area >1000 m2 g−1, and a micropore diameter of 1.4 nm close to mesopore values. Collectively, these data establish CaSyr-1 as one of the most porous bioMOFs reported to date, with high molecular adsorption capacity. The CaSyr-1 adsorptive behavior is revised here through the reversible adsorption of CO2 and the encapsulation of bioactive ingredients in the structure. Remarkably, CaSyr-1 enables the development of triple therapeutic entities, involving bioactive Ca2+, syringic acid and an impregnated drug.

Graphical abstract: Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

Supplementary files

Article information

Article type
Research Article
Submitted
10 дек 2022
Accepted
01 мар 2023
First published
02 мар 2023
This article is Open Access
Creative Commons BY-NC license

Inorg. Chem. Front., 2023,10, 2165-2173

Facile, fast and green synthesis of a highly porous calcium-syringate bioMOF with intriguing triple bioactivity

A. Rosado, O. Vallcorba, B. Vázquez-Lasa, L. García-Fernández, R. A. Ramírez-Jiménez, M. R. Aguilar, A. M. López-Periago, C. Domingo and J. A. Ayllón, Inorg. Chem. Front., 2023, 10, 2165 DOI: 10.1039/D2QI02639B

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements