Issue 30, 2020

A phenol phosphorescent microsensor of mesoporous molecularly imprinted polymers

Abstract

Based on the optical quenching phenomenon, a smart mesoporous phosphorescent microsensor was built. It is a phenol microsensor, which inherits a high selectivity of molecularly imprinted polymers (MIPs) and room-temperature phosphorescence (RTP) properties of Mn-doped ZnS quantum dots (QDs). On the surface of silane-modified Mn-doped ZnS QDs, the phenol microsensor was synthesized by a sol–gel process. Because of the presence of a porogenic agent, a mesoporous structure played an important role in increasing the detection sensitivity. The MPTS-modified Mn-doped ZnS QDs were used as solid supports and auxiliary monomers. Under optimal conditions, the experiment for the detection of phenol had a linear range of 5.0 to 50 μmol L−1 with a correlation coefficient of 0.9983 and a high imprinting factor (IF) of 3.28. In addition, the as-prepared Mn-doped ZnS QD@ms-MIPs were successfully applied for phenol determination and selectivity in water samples. Therefore, this study provides a highly selective and sensitive mesoporous phosphorescent microsensor for the detection of phenol.

Graphical abstract: A phenol phosphorescent microsensor of mesoporous molecularly imprinted polymers

Article information

Article type
Paper
Submitted
28 мар 2020
Accepted
20 апр 2020
First published
09 май 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 17906-17913

A phenol phosphorescent microsensor of mesoporous molecularly imprinted polymers

X. Lv and P. Gao, RSC Adv., 2020, 10, 17906 DOI: 10.1039/D0RA02834G

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements