Issue 11, 2018

Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles

Abstract

The hydrolysis reaction between Brønsted basic organometallic or metal–amide reagents with Brønsted acidic OH groups from water or metal–hydroxides may act as a controlled stoichiometric strategy for the formation of M–O–M bonds, if careful consideration of reaction conditions is employed. This article explores the utilisation of highly reactive organometallic and metal–amide complexes from across the periodic table as reagents for the synthesis of metal-oxo clusters, oxo-bridged heterobimetallics and metal oxide nanoparticles. Such reactivity typically occurs at low temperatures with the release of hydrocarbon or amine by-products. The impact of ligand coordination, M–C bond strength, M–OH acidity and reaction temperature are discussed.

Graphical abstract: Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles

Article information

Article type
Perspective
Submitted
02 янв 2018
Accepted
24 фев 2018
First published
26 фев 2018

Dalton Trans., 2018,47, 3638-3662

Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles

J. A. Garden and S. D. Pike, Dalton Trans., 2018, 47, 3638 DOI: 10.1039/C8DT00017D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements