Issue 9, 2018

A chemical redox reaction to generate rock salt-type materials: the case of Na3V2O5

Abstract

Chemical redox reactions are extremely efficient to prepare fully reduced or oxidized phases that are formed during the topotactic insertion/extraction of alkaline ions. Herein, we report these reactions and discuss the possibility to generate new ordered or disordered rock salt-type structures depending on the structure of the mother phase. We have shown that a disordered rock salt-type structure is formed when the transition element is located at the tetrahedral site, as exemplified by the formation of Na3V2O5 upon chemical reduction of V2O5.

Graphical abstract: A chemical redox reaction to generate rock salt-type materials: the case of Na3V2O5

Article information

Article type
Paper
Submitted
21 ноя 2017
Accepted
22 дек 2017
First published
22 дек 2017

Dalton Trans., 2018,47, 3112-3118

A chemical redox reaction to generate rock salt-type materials: the case of Na3V2O5

E. Adamczyk, E. Anger, M. Freire and V. Pralong, Dalton Trans., 2018, 47, 3112 DOI: 10.1039/C7DT04377E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements