Issue 1, 2015

A multiscale approach to the adsorption of core–shell nanoparticles at fluid interfaces

Abstract

Self-assembly of colloidal particles at liquid–liquid interfaces is a process with great potential for the creation of controlled structures, due to the trapping of the particles in the plane of the interface combined with their lateral mobility. Here we present a multiscale characterisation of the adsorption and interfacial behaviour of core–shell iron oxide–poly(ethylene glycol) nanoparticles at a water–n-decane interface using three complementary, in situ, methods, which span many different length scales. First, dynamic interfacial measurements are taken to follow the adsorption of particles from the bulk aqueous phase to the interface. The mechanical properties of the interface are then probed using micron-sized tracers in probe-particle tracking and nano-tracers in fluorescence correlation spectroscopy. The results show that the rate of particle adsorption to the interface scales with the square of bulk concentration, as predicted by a recent model. In addition, we show that despite full monolayers of nanoparticles forming, the interface remains unexpectedly fluid, with only a slowing of tracer particle mobility but no evidence of interface jamming as seen for hard nanoparticles. Our results illustrate that nanoparticles stabilised by soft, extended polymeric shells, display distinct features at fluid interfaces that can be harnessed for the fabrication of functional materials.

Graphical abstract: A multiscale approach to the adsorption of core–shell nanoparticles at fluid interfaces

Article information

Article type
Paper
Submitted
24 авг 2014
Accepted
27 окт 2014
First published
27 окт 2014
This article is Open Access
Creative Commons BY license

Soft Matter, 2015,11, 118-129

A multiscale approach to the adsorption of core–shell nanoparticles at fluid interfaces

A. Nelson, D. Wang, K. Koynov and L. Isa, Soft Matter, 2015, 11, 118 DOI: 10.1039/C4SM01881H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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