Issue 3, 2015

Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

Abstract

We report two porous Zr phosphonate frameworks. The kinetic product, ZrH2L-A, shows low order and is less porous. An HF-modulated structure, CALF-31, is more ordered and has higher porosity. While not single crystalline, CALF-31 is highly robust and the CO2 heats of adsorption give insights into ordering in phosphonate MOFs.

Graphical abstract: Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

Supplementary files

Article information

Article type
Research Article
Submitted
24 ноя 2014
Accepted
22 янв 2015
First published
03 фев 2015

Inorg. Chem. Front., 2015,2, 273-277

Author version available

Reconciling order, stability, and porosity in phosphonate metal–organic frameworks via HF-mediated synthesis

R. K. Mah, B. S. Gelfand, J. M. Taylor and G. K. H. Shimizu, Inorg. Chem. Front., 2015, 2, 273 DOI: 10.1039/C4QI00209A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements