Issue 10, 2014

Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

Abstract

In most kinetic investigations of catalytic reactions, catalytic activity is a traditionally measured kinetic parameter. However, differential selectivity measurements have many advantages for mechanistic studies. This Perspective gives an overview of the basic principles and practices of mechanistic studies based on differential selectivity measurements, including the use of artificially created competitive reactions.

Graphical abstract: Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

Supplementary files

Article information

Article type
Perspective
Submitted
14 апр 2014
Accepted
29 май 2014
First published
29 май 2014

Catal. Sci. Technol., 2014,4, 3439-3457

Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

A. F. Schmidt, A. A. Kurokhtina and E. V. Larina, Catal. Sci. Technol., 2014, 4, 3439 DOI: 10.1039/C4CY00479E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements