Issue 34, 2013

Transition metal-catalyzed decarboxylative coupling reactions of alkynyl carboxylic acids

Abstract

The decarboxylative coupling of alkynyl carboxylic acids is an attractive area of research in organic chemistry, because the structure of aryl alkyne is one of the important building blocks for the synthesis of p-conjugated compounds. The use of alkynyl carboxylic acid as an alkyne source has several advantages in handling and storage. As a catalyst, palladium, copper, nickel, and silver were employed in the decarboxylative coupling reactions. The formation of C–C (sp2–sp, sp–sp and sp3–sp), C–N, C–P and C–S bonds has been developed. This review aims to illustrate the development of the decarboxylative coupling reaction of alkynyl carboxylic acids.

Graphical abstract: Transition metal-catalyzed decarboxylative coupling reactions of alkynyl carboxylic acids

Supplementary files

Article information

Article type
Review Article
Submitted
24 мар 2013
Accepted
31 май 2013
First published
31 май 2013

RSC Adv., 2013,3, 14165-14182

Transition metal-catalyzed decarboxylative coupling reactions of alkynyl carboxylic acids

K. Park and S. Lee, RSC Adv., 2013, 3, 14165 DOI: 10.1039/C3RA41442F

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