Issue 33, 2021

The hydroboration of α-diimines

Abstract

The uncatalyzed addition of catecholborane to α-diimines has been examined. Reactions proceed smoothly at room temperature in the absence of a catalyst or additive, providing bis-hydroboration products with 3-coordinate boron centres or mono-hydroboration products with 4-coordinate boron centres, depending on the nature of the diimine reagent.

Graphical abstract: The hydroboration of α-diimines

Supplementary files

Article information

Article type
Communication
Submitted
01 мар 2021
Accepted
13 апр 2021
First published
15 апр 2021

New J. Chem., 2021,45, 14908-14912

The hydroboration of α-diimines

S. J. Geier, J. F. Binder, C. M. Vogels, L. K. Watanabe, C. L. B. Macdonald and S. A. Westcott, New J. Chem., 2021, 45, 14908 DOI: 10.1039/D1NJ01025E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements