This paper describes a novel method to obtain a new class of red-shifted azoimidazole dyes with antimicrobial and halochromic properties through an interesting domino rearrangement, and using an affordable and environmentally benign oxidant system.
Glioblastoma multiforme (GBM) is an aggressive and treatment-resistant brain tumor.
Artificial nitroalkane oxidases based on catalytic amounts of flavins enable nitroalkane umpolung resulting in β-nitroalcohols. Two alternative pathways via flavin-5-iminium species are possible.
Ultrasound-assisted synthesis of MOF-235(Fe) and PVP accelerates its phase transition to MIL-53(Fe).
An urgent need for quantitative mechanistic understanding of advanced redox processes for aqueous electrocatalytic organohalogen destruction methods is addressed, highlighting remediation of fluorinated, chlorinated, and brominated water pollutants.