H8-BINOL is incorporated for the first time in a metal–organic framework displaying exceptional selectivity as a fluorescence chiral sensor for aspartic acid dimethyl ester.
The paper describes the enantioselective synthesis of 5-monosubstituted hydantoins via chiral phosphoric acid-catalysed condensation of glyoxals and ureas at room temperature.
A novel fluorescent “off” sensor, R-β-D-1, was obtained in high yield (91.2%) by using octahydronaphthol as a backbone, introducing an alkyne group at the 2-position, and linking azido-glucose via a click reaction.
We describe an enantioselective C-7 Friedel–Crafts alkylation reaction of 4-amino indoles with α-aryl enamides catalyzed by chiral H8-BINOL derived phosphoric acids.
This review aims to collect advancements in enantioselective palladium-catalyzed cyclization reactions over the past eleven years, and it is organized into thirteen sections depending on the different types of transformations involved.