Formulating cathode materials based on high-entropy strategies for sodium-ion batteries

Zhuozheng Hong, Zhuang-Chun Jian, Yan-Fang Zhu, Yan-Jiang Li, Qi-Cong Ling, Hanshen Xin, Didi Wang, Chao Wu and Yao Xiao

Chem. Sci., 2025, 16, 17058
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Unlocking the structure and cation synergistic modulation of Prussian blue analogues with double redox mechanism for improved aqueous nonmetallic ion storage

Hao Fu, Lingqian Ye and Jun Yang

Dalton Trans., 2024, 53, 16128
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Enhanced redox kinetics of Prussian blue analogues for superior electrochemical deionization performance

Jiabao Li, Ruoxing Wang, Lanlan Han, Tianyi Wang, Zeinhom M. El-Bahy, Yiyong Mai, Chengyin Wang, Yusuke Yamauchi and Xingtao Xu

Chem. Sci., 2024, 15, 11814
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A novel strategy for the reduction of coordinated water in Prussian blue analogues for their application as cathode materials for sodium-ion batteries

Xin Xu, Shiji Zhu, Chen Yang, Yongdong Wang, Zhennan Wu, Junzi Zheng, Jie Wu and Yunfang Gao

J. Mater. Chem. A, 2025, 13, 11848
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Improving upon rechargeable battery technologies: on the role of high-entropy effects

Zihao Zhou, Yuan Ma, Torsten Brezesinski, Ben Breitung, Yuping Wu and Yanjiao Ma

Energy Environ. Sci., 2025, 18, 19
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High-entropy conductive manganese-based Prussian blue analogue cathode for high-performance ammonium ion storage

Zining Li and Liubing Dong

Inorg. Chem. Front., 2026, 13, 3291
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Breaking the boundaries of Li–S batteries with high-entropy engineered multifunctional materials

Suo Li, Libo Li, Hang Yang, Zhixuan Wang, Xiangrui Deng, Wenyi Lu and Wenhao Xu

Energy Environ. Sci., 2026, 19, 1458
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Recent advances in high-entropy materials for efficient alkali metal-ion batteries

Liping Duan, Yichen Du, Yijiang Liu, Haowei Tang, Chi Zhou, Dong Ha Kim, Zhiqun Lin and Xiaosi Zhou

Chem. Soc. Rev., 2025, 54, 11740
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Ultrafast biphasic Na5V3(PO4)2(P2O7)2/C composite cathode for sodium-ion batteries

Yu Bai, Yunyun Liu, Yangyang Zhang, Ruisi Jiang and Xingde Xiang

Chem. Commun., 2025, 61, 4860
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Hydrophobic Lattice Engineering of Prussian Blue Analogs with Accelerated Redox Kinetics for High-Areal-Capacity Sodium-Ion Battery Electrodes

Xihao Lin, Boao Zhou, Shiyi Xu, Hang Zhang, Yameng Fan, Zhijin Ju, Yun Gao, Li Li, Jiazhao Wang and Shulei Chou

ACS Nano, 2025, 19, 31023
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Recent advances in Prussian blue analogues as cathode materials for sodium-ion batteries

Bofeng Zhang, Jianhua Zhang, Yingxue He, Kailing Zhou and Hao Wang

Journal of Energy Chemistry, 2025, 110, 593
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Rational construction of ZnCdSe/Ni-Co prussian blue analog heterojunction with a built-in electric field for efficient photocatalytic hydrogen evolution

Shuya Zhang, Zhenyu An, Bo Wen, Jiayue Liu, Xin Guo, Yafeng Liu and Zhiliang Jin

Journal of Alloys and Compounds, 2025, 1037, 182357
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Prussian blue analogues for advanced non-aqueous sodium ion batteries: Redox mechanisms, key challenges and modification strategies

Lina Zhao, Shangyi Bi, Junyi Li, Yuhao Wen, Hongjian Zhang, Dan Zhang, Shanshan Lu, PeiPei Yin, Fanian Shi, Jie Yan, Shanshan Pan and Haitao Zhang

Energy Storage Materials, 2025, 78, 104256
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High-Entropy Oxides: A strategy for Next-Generation lithium and Sodium-Ion battery electrodes

Yujia Wu, Mili Liu, Anwei Zhang, Longtao Ma and Liuzhang Ouyang

Materials Today, 2025, 88, 1028
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Rational design of Core-Shell heterostructured CoFe@NiFe Prussian blue analogues for efficient capacitive deionization

Bin Zhao, Yang Wang, Zhuo Wang, Yuting Hu, Jingyuan Zhang and Xue Bai

Chemical Engineering Journal, 2024, 487, 150437
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Crystal structure, synthesis, problems, and solutions for Prussian blue analogue cathodes for high-energy and low-cost sodium-ion batteries based on recent research

Kouthaman Mathiyalagan, Rubini Raja and Young-Chul Lee

Coordination Chemistry Reviews, 2026, 552, 217543
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Investigating the Impact of Copper and Zinc Doping in High‐Entropy Prussian Blue Analogues for Na‐Ion Batteries: From Material Analysis to Device Fabrication

Pappu Naskar, Pallav Mondal, Biplab Biswas, Sourav Laha and Anjan Banerjee

Energy Tech, 2025, 13
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High-entropy materials for sodium-ion batteries

Greeshma Caroline, Neeraja Nair, Shantikumar V. Nair, Prabeer Barpanda and Senthilkumar Baskar

Next Sustainability, 2024, 4, 100044
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Multifunctional cyclodextrins modification of Prussian blue improving its stability and kinetic performance in sodium-ion batteries

Jiayu Peng, Zhiruo Zhang, Chengfang La, Tong Zhou, Yan Long, Jing Xu, Yuhao Song, Lihong Xue and Wuxing Zhang

Journal of Electroanalytical Chemistry, 2026, 1000, 119649
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Decoding the functional roles of multimetallic constituents in high-entropy prussian blue analogues for sodium-ion batteries

Zilong Zhu, Siwei Fan, Jian Chen, Xiangwu Chang, Wenjun Xu, Mofan Li, Baojia Dai, Li Li, Yang Liu and Yun Qiao

Journal of Colloid and Interface Science, 2026, 702, 138824
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Highly Crystalline Multivariate Prussian Blue Analogs via Equilibrium Chelation Strategy for Stable and Fast Charging Sodium‐Ion Batteries

Yichao Wang, Jiahe Liu, Ning Jiang, Jianhua Yang, Cheng Yang and Yu Liu

Small, 2024, 20
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Entropy‐Production Type Prussian Blue Analogues: A Family of Promising Hosts for High‐Performance Multivalent‐Ion Batteries

Ying‐Di Ge, Xin‐Yang Zhou, Wei Shang, Yue Liu, Hong‐Jie Zhong, Jun‐Ming Cao and Xing‐Long Wu

Chemistry A European J, 2025, 31
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Tailored core-shell PW@PB cathodes for enhanced sodium-ion battery stability and rate capability

Yuan Wang, Qinfeng Zheng, Yuepeng Pang, Yixiao Zhang, Tao Yuan and Shiyou Zheng

Journal of Energy Storage, 2025, 111, 115424
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Boosting ultralong lifespan of Fe-based Prussian blue analogs cathode via element doping and crystal water capture

Xuan Wang, Mengran Zhao, Wenjing Du, Chaomin Zhang, Wenyao Li, Cheng Yang and Yu Liu

Chemical Engineering Journal, 2025, 508, 160997
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High-entropy non-oxide ceramics: Cracking the multi-element code for next-gen energy storage

Xuefeng Liu, Boya Hu, Aiqin Mao, Haijun Zhang, Gaoqian Yuan, Yanhua Ding and Wen Lei

Composites Part B: Engineering, 2026, 310, 113152
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Advancing sodium-ion batteries for sustainable energy storage

Muhammad Faizan and Mohammad Nahid Siddiqui

Journal of Power Sources, 2026, 679, 240162
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Recent advancements of high entropy ceramic/carbon composites toward rechargeable batteries

Huijun Li, Xiaoqin Cheng, Jinyu Zhao, Mingyang Gao, Hao Xu and Xiaomin Wang

Journal of Alloys and Compounds, 2025, 1010, 178237
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Unraveling the regulation rules of vanadium-site cation substitution for Na3V2(PO4)3 cathode materials toward high energy density sodium-ion batteries

Yi-Meng Wu, Jing-Yu Wang, Hao-Tian Guo, Peng-Fei Wang, Zong-Lin Liu, Yan-Rong Zhu, Jie Shu and Ting-Feng Yi

Green Energy & Environment, 2026, 11, 62
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Entropically Stabilized Compositionally Complex Prussian Blue Analogues in Electrochemical Energy Storage and Catalytic Applications

Madakannu Iyyappan, Chenrayan Senthil and Debasis Ghosh

Advanced Energy Materials, 2026, 16
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High-Entropy Prussian Blue Analogues as High-Capacity Cathode Material for Potassium Ion Batteries

Wenlong Yan, Xi Feng, Xin Min, Bin Ma, Yangai Liu, Ruiyu Mi, Xiaowen Wu, Wei Wang, Zhaohui Huang and Minghao Fang

J. Electrochem. Soc., 2024, 171, 080529
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Dual carbon decorated Na3.5Mn0.5V1.5(PO4)3 cathode with high-density and long-cycling span-life for sodium-ion batteries

Fengqi Lu, Yidan Lu and Longzhu Zhao

Journal of Power Sources, 2025, 645, 237194
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Recent Progress in Prussian Blue Analog Nanomaterials: Structural Engineering and Functional Applications

Ke Wu, Guangxun Zhang, Bingyi Yan and Huan Pang

ChemSusChem, 2026, 19
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High-Entropy and Component Stoichiometry Tuning Strategies Boost the Sodium-Ion Storage Performance of Cobalt-Free Prussian Blue Analogues Cathode Materials

Yuan-Ting Lin, Bai-Tong Niu, Zi-Han Wang, Yu-Xi Li, Yun-Peng Xu, Shi-Wei Liu, Yan-Xin Chen and Xiu-Mei Lin

Molecules, 2024, 29, 4559
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Key issues, material design and application of Prussian blue and its analogues composites in metal-ion based energy storage devices

Xueyin Wu, Qingyang Zhang, Xiaocheng Zhou, Yun Zhao, Nguyen Duc Hoa, Ronghua Zeng, Zhongzhi Yuan and Xing-Long Wu

Chemical Engineering Journal, 2025, 525, 170281
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Dual-metal CuFe/Fe cube nanozyme with Prussian blue analogue for highly efficient colorimetric immunoassay

Shuqun Lao, Haiyang Wang, Di Wu, Qiaohua Wei and Dianping Tang

Biosensors and Bioelectronics, 2025, 287, 117689
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Spherical Mg/Cu Co‐Doped Na4Fe3(PO4)2P2O7 Cathode Materials with Mitigated Diffusion‐Induced Stresses and Enhanced Cyclic Stability

Fan Peng, Pengyuan Dong, Changdong Chen, Youqi Chu, Wenxue Min, Anjie Lai, Hao Wang and Chenghao Yang

Angewandte Chemie, 2025, 137
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Intelligent synthesis of nano Prussian blue analogue based hybrids for high performance in lithium-ion batteries

Yuxin Shi, Biao Yang, Gongjing Song, Zheng Liu, Zhan Zhang, Mohsen Shakori and Huan Pang

Sci. China Chem., 2025, 68, 4194
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Prussian Blue Analogs as Cathode Materials for Sodium‐Ion Batteries

Narasimharao Kitchamsetti, Ana L. F. de Barros and Sungwook Mhin

Batteries & Supercaps, 2025, 8
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Prussian Blue Analogues for Sodium‐Ion Battery Cathodes: A Review of Mechanistic Insights, Current Challenges, and Future Pathways

Yang Xiao, Jun Xiao, Hangkai Zhao, Jiayi Li, Guilai Zhang, Dingyi Zhang, Xin Guo, Hong Gao, Yong Wang, Jun Chen, Guoxiu Wang and Hao Liu

Small, 2024, 20
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Revitalizing Prussian Blue Cathodes: Dynamic Self‐Healing in Dilute Aqueous Electrolytes for Ultra‐Stable Potassium‐Ion Batteries

Jingqi Wang, Yuanxu Wang, W. L. Qubie, Erqing Xie, Jiecai Fu and Bingan Lu

Adv Funct Materials, 2026, 36
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Crystal water-capturing and film-forming bifunctional electrolyte additive for stabilizing sodium iron hexacyanoferrate cathode for Na-ion batteries

Xianhai Bai, Longqing Zhang, Dashui Zhang, Kaiming Li, Tongcan Li, Yang Ren, Huibing He, Bingxing Xie, Gang Sun, Jing Xu and Xucai Yin

Chemical Engineering Journal, 2024, 497, 154902
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Dissolution Inhibition Strategy Stabilizes Manganese Prussian Blue Analogs for High‐Energy Sodium‐Ion Batteries

Yichao Wang, Cheng Yang, Lingbo Yao, Ning Jiang, Jiahe Liu, Shouyu Sun, Xinyu Wang, Jianhua Yang and Yu Liu

Adv Funct Materials, 2025, 35
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High-entropy iron phosphide/carbon nanostructures: Advanced anodes boosting sodium-ion storage capacity and long-term stability

Zhipeng Qin, Shuling Liu, Tianle Liu, Jiafei Niu, Kexin Cao, Yakun Zhang, Muxuan Luo, Xuexia Song and Jianbo Tong

Journal of Energy Storage, 2026, 154, 121084
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Engineering MOFs for advanced metal-ion batteries: from structural design to performance optimization

Tingting Lv, Qixian Huang, Jie Liu, Qianli Zhang, Bin He, Qiyan Shen, Jie Liu, Yuyang Zhou and Huan Pang

Coordination Chemistry Reviews, 2026, 557, 217690
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Innovative High‐Entropy Strategy Extending Traditional Metal Substitution for Optimizing Prussian Blue Analogues in Rechargeable Batteries

Zihao Zhou, Yutao Dong, Yuan Ma, Hehe Zhang, Fanbo Meng, Yanjiao Ma and Yuping Wu

SusMat, 2025, 5
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Spatially confined Co nanoparticles in N doped carbon material for high efficiency capacitive deionization

Jianwei Wu, Yuzudi Tong, Xinhua Huang, Dongyin Qin, Ruikun Zhao, Ru Li and Guangzhi Hu

Desalination, 2025, 600, 118479
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Achieving Ultra‐Fast and Stable Sodium‐Ion Batteries Through Deep Activation of Low‐Spin Iron in Prussian Blue

Dong Yang, Haonan Wang, Yue Zhao, Mengting Guo, Di Xie, Nankai Wang, Fei Wang, Changping Wang, Tianyi Li, Yan He, Mingyue Ruan and Qiang Li

Adv Funct Materials, 2025, 35
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From Na to K‐Based Prussian Blue: A Path Toward Cathode Materials for Extreme Environment

Zheng Xu, Shuangyu Liu, Jian Xie, Aijun Zhou, Jicheng Jiang, Yinda Li, Yunhao Lu, Yang Nie, Xiongwen Xu, Jian Tu, Bo Xu, Peng Zhang and Xinbing Zhao

Adv Funct Materials, 2025, 35
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From Materials to Systems: Challenges and Solutions for Fast‐Charge/Discharge Na‐Ion Batteries

Bonyoung Ku, Sangbin Park, Sunha Hwang, Sunghyun Lim, Won‐Sub Yoon and Jongsoon Kim

Advanced Energy Materials, 2025
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Heterointerface engineering via dual modification stabilizes O3-type layered oxides cathodes for high-voltage sodium-ion batteries

Wei Li, Wei Huang, Man Zhang, Xiaobing Guan, Yongjie Jiang, Wenji Yin, Kui Liu, Qichang Pan, Sijiang Hu, Hongqiang Wang, Qingyu Li and Fenghua Zheng

Journal of Colloid and Interface Science, 2026, 715, 140265
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Ultralong Lifespan Zero‐Cobalt/Nickel Prussian Blue Analogs Cathode Realized by Solid Solution Reaction Sodium Storage Mechanism

Yichao Wang, Ning Jiang, Jiahe Liu, Shouyu Sun, Xinyu Wang, Jianhua Yang, Cheng Yang and Yu Liu

Adv Funct Materials, 2024, 34
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High-Entropy Materials: A New Paradigm in the Design of Advanced Batteries

Yangmei Xin, Minmin Zhu, Haizhong Zhang and Xinghui Wang

Nano-Micro Lett., 2026, 18
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Leveraging Sodium Storage of Water-Deficient Prussian Blue Analogues by Deep Eutectic Chemistry

Mingwei Jiang, Yiming Zhao, Zhidong Hou, TaiXiang Li, Xirui Wei, Fengxuan Wu, Fei Xu, Feiyu Kang and Jian-Gan Wang

ACS Energy Lett., 2026, 11, 526
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High-entropy design principles for sodium-based electrochemical energy storage systems

S.G. Siddanth and Tiju Thomas

Coordination Chemistry Reviews, 2026, 556, 217667
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Flexible zinc-ion hybrid supercapacitor based on Co2+-doped polyaniline/V2O5 electrode

Yong Xu, Xijia Yang, Xuesong Li, Yang Gao, Liying Wang and Wei Lü

Journal of Power Sources, 2024, 623, 235399
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Layered-Structured Sodium-Ion Cathode Materials: Advancements through High-Entropy Approaches

Yutao Dong, Zihao Zhou, Yuan Ma, Hehe Zhang, Fanbo Meng, Yuping Wu and Yanjiao Ma

ACS Energy Lett., 2024, 9, 5096
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Co-doped Ni-PBA anchored on optimized ZIF-67-derived Co/N-doped hollow carbon framework for high-performance hybrid capacitive deionization

Bingying Li, Yue Wang, Shunjiang Huang, Rongli Fang, Le Zhang, Ying Jin and Kaiwen Guo

Separation and Purification Technology, 2025, 358, 130257
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Emerging high-entropy materials for rechargeable batteries

Youcun Bai, Heng Zhang, Yuehao Gu, Xunzhu Zhou, Jiazhao Wang, Wenhao Liang, Shixue Dou and Lin Li

Matter, 2026, 9, 102556
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Self-assembled high-entropy Prussian blue analogue nanosheets enabling efficient sodium storage

Yunjiang Gu, Yonglin Lu, Pengfei Dai, Xin Cao, Yiming Zhou, Yawen Tang, Zhiwei Fang and Ping Wu

Journal of Colloid and Interface Science, 2025, 677, 307
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Tri-site co-doping NASICON-type Na0.97K0.03Ti1.95Al0.05(PO4)2.95(SiO4)0.05/C with enhanced rate performance and cycling stability

Mengran Zhao, Wenjing Du, Xuan Wang, Wenyao Li, Cheng Yang and Yu Liu

Journal of Materials Science & Technology, 2026, 245, 301
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In Situ Balanced Synthesis of High-Activity Low-Spin Iron Cathode Prussian Blue for Enhanced Sodium-Ion Storage

Zhiheng Su, Zihao Li, Xijia Yang, Xuesong Li, Liying Wang and Wei Lü

Nano Lett., 2025, 25, 957
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High-entropy materials for high-performance rechargeable batteries: Concepts, synthesis, and development

Xiaohan Du, Zihang Zhang, Chenxi Sun, Mengmeng Zhen, Zhenzhong Hu and Huiling Liu

Journal of Alloys and Compounds, 2025, 1036, 181806
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Spherical Mg/Cu Co‐Doped Na4Fe3(PO4)2P2O7 Cathode Materials with Mitigated Diffusion‐Induced Stresses and Enhanced Cyclic Stability

Fan Peng, Pengyuan Dong, Changdong Chen, Youqi Chu, Wenxue Min, Anjie Lai, Hao Wang and Chenghao Yang

Angew Chem Int Ed, 2025, 64
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Research progress of prussian blue analogues for cathode of sodium ion batteries

Mingjun Xiao

Journal of Alloys and Compounds, 2025, 1036, 182014
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Prussian blue analogue as cathode materials in sodium ion batteries: A review

Ganya Goel, Mamta Sharma and S.K. Tripathi

Journal of Energy Storage, 2025, 126, 116995
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Correlating storage mechanism and solid electrolyte interphase kinetics for high-rate performance of hard carbon anode in ether electrolytes for sodium-ion batteries

Sanchita Manna, Prakhar Verma and Sreeraj Puravankara

Journal of Power Sources, 2025, 631, 236234
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Se-vacancy-rich MnSe1-x nanocubes with in situ coated carbon as fast-kinetics anodes for sodium-ion half/full batteries

Chao Li, Xing Jin, Zhiying Du, Zichao Xia, Man Huang, Qing Li, Xing Zhang, Kangzhe Cao and Yu Zhang

Journal of Energy Storage, 2026, 152, 120616
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