One-pot route to aryl halide/sulfur/olefin terpolymers via sequential crosslinking by radical-initiated aryl halide-sulfur polymerization, inverse vulcanization, and sulfenyl chloride formation

Nawoda L. Kapuge Dona and Rhett C. Smith

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DOI: 10.1039/D5PY00548E

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Nicola Bragato, Lazaros Papadopoulos, Andrea Pasquale, Sacha Pérocheau Arnaud, Minna Hakkarainen, Alessandro Pellis and Tobias Robert

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DOI: 10.1039/D5GC06888F

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Yuzhao Qi, Yinliang Zhang, Shiyu Ou, Guangwu Zhuo, Hongju Zeng, Yufei Lao, Junfeng Wang, Qingwen Wang and Chuigen Guo

Green Chem., 2025, 27, 13385
DOI: 10.1039/D5GC04554A

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J Polym Environ, 2026, 34
DOI: 10.1007/s10924-025-03736-9

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Xianjie Pan, Zhaoyi Luo, Fanqi Liu, Quanqian Yi and Yanning Zeng

Industrial Crops and Products, 2024, 208, 117779
DOI: 10.1016/j.indcrop.2023.117779

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Liang Gao, Hao Wang, Xuan Yao, Zhiran Zheng, Liyu Wang, Zixuan Wang, Yonggui Wang, Baoyan Zhang, Xianghai Jing and Jianqiao Wu

Front. Mater., 2025, 12
DOI: 10.3389/fmats.2025.1552713

Reprocessable CO2–Based Thermosets via Copolymerization of Elemental Sulfur with a δ-Lactone Derived from CO2 and Butadiene

Chao-Ji Xie, Zong-Bin Lu, Yu Xiong, Lei Xia, Li-Min Wu, Chun-Yan Hong, Ye-Zi You and Ze Zhang

Macromolecules, 2026, 59, 2126
DOI: 10.1021/acs.macromol.5c03307

Controllable Modification of Rubber Achieved through Biobased Inverse Vulcanized Compounds

Hailan Kang, Jiayu Shi, Long Li, Feng Yang, Donghan Li and Qinghong Fang

ACS Appl. Polym. Mater., 2025, 7, 7283
DOI: 10.1021/acsapm.5c00852

Synthesis of Dynamic Polyurethanes by Utilizing Low-Transition-Temperature Mixtures of Pyrogallol and Poly(ethylene glycol)

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ACS Appl. Polym. Mater., 2024, 6, 8786
DOI: 10.1021/acsapm.4c00874

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Zhou-Liang Wu, Hao-Jia Guo, Ling-Rui Li, Shuangquan Liao and Ming-Chao Luo

Macromolecules, 2026, 59, 1499
DOI: 10.1021/acs.macromol.5c02859

High-performance epoxy vitrimer with balanced thermomechanical properties and repairability via benzoxazine modification

Yang Liu, Jia Du, Kexin Fu, Rong Sun and Pengli Zhu

Materials Letters, 2026, 412, 140387
DOI: 10.1016/j.matlet.2026.140387

A Decade Development of Inverse Vulcanization Towards Green and Sustainable Practices

Hang Shen, Botuo Zheng and Huagui Zhang

Polymer Reviews, 2024, 64, 1211
DOI: 10.1080/15583724.2024.2382891

Rational design of biomass-derived and UV-curable dynamic polymer for the encapsulation of paper-based flexible strain sensor

Jinhong Hao, Hanbin Liu, Shiyu Du, Huacui Xiang, Guodong Liu, Zhijian Li and Hongwei Zhou

Materials Today Sustainability, 2024, 26, 100756
DOI: 10.1016/j.mtsust.2024.100756

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ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202500480

Mechanically Strong and Tough Plant Oil-Based Poly(ester amide) Vitrimers with Closed-Loop Recyclability

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ACS Sustainable Chem. Eng., 2024, 12, 2668
DOI: 10.1021/acssuschemeng.3c06783

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Wenyan Zhang, Deguang Liu, Yuting Chu, Fengcheng Li, Lei Huang, Xueli Liu, Lizhi Xu, Xi Lu, Chuang Li and Yao Fu

Adv Funct Materials, 2026
DOI: 10.1002/adfm.202531566

Green synthesis of soybean oil-derived UV-curable resins for high-resolution 3D printing

Xinqi Wang, Xinxin Cai, Jiwen Hu, Jiayi Li, Ruixiang Zhou and Shudong Lin

Additive Manufacturing, 2024, 95, 104543
DOI: 10.1016/j.addma.2024.104543

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Ankit Sharma, Sandeep Singh Bisht, Muskan Kumari, Manju Yadav, Harsh Saini, Shipra Jaswal, Inderdeep Singh and Bharti Gaur

Materials Today Sustainability, 2026, 33, 101275
DOI: 10.1016/j.mtsust.2025.101275

Bio-based eco-friendly coatings with multi-mechanism anticorrosion design and advanced thermal conductivity

Xinqi Wang, Xinxin Cai, Jiayi Li, Ruixiang Zhou, Xuefeng Gui, Jiwen Hu and Shudong Lin

Corrosion Science, 2025, 257, 113276
DOI: 10.1016/j.corsci.2025.113276

Itaconic acid-based sustainable polyurethane covalent adaptable networks with robust mechanical, reshaping and UV-resistant properties based on reversible disulfide bond

Fangfang Kong, Xiaozhen Ma, Xiaobo Xu, Minghui Cui, Honglong Zhao, Jin Zhu and Jing Chen

Materials Today Chemistry, 2024, 35, 101881
DOI: 10.1016/j.mtchem.2023.101881

Bio-based polyurethane triboelectric nanogenerator with superior low-temperature self-healing performance for unmanned surveillance

Hong Wang, Linman Zhang, Ziyue Su, Chaoyu Chen, Weijun Yang, Pengwu Xu, Deyu Niu, Pibo Ma and Piming Ma

Nano Energy, 2024, 130, 110144
DOI: 10.1016/j.nanoen.2024.110144

From biomass to vitrimers: Latest developments in the research of lignocellulose, vegetable oil, and naturally-occurring carboxylic acids

Yanfan Yang, Haibo Liu, Biying Lin, Dexi Tang, Jikun Xu, Lin Dai and Chuanling Si

Industrial Crops and Products, 2023, 206, 117690
DOI: 10.1016/j.indcrop.2023.117690