Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation

Amal Bouammali, Anaïs Coffinet, Laure Vendier and Antoine Simonneau

Dalton Trans., 2022, 51, 10697
DOI: 10.1039/D1DT03905A

Coordination-induced bond weakening and small molecule activation by low-valent titanium complexes

Ugochinyere N. Oloyede and Robert A. Flowers

Dalton Trans., 2024, 53, 2413
DOI: 10.1039/D3DT03454B

Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies

Jannik Junge, Sven Froitzheim, Tobias A. Engesser, Jan Krahmer, Christian Näther, Nicolas Le Poul and Felix Tuczek

Dalton Trans., 2022, 51, 6166
DOI: 10.1039/D1DT04212B

Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR)

Bijoy Ghosh, Sahtaz Ahmed and Ashwini K. Phukan

Dalton Trans., 2024, 53, 19179
DOI: 10.1039/D4DT02217C

Fullerene–porphyrin nanosheets as an efficient catalyst enable solar-light-driven ammonia synthesis

Tao Wang, Yupeng Song, Chong Wang, Hongyi Wang, Youpeng Zhang, Ying Jiang, Tianyang Dong, Bo Wu and Chunru Wang

Chem. Commun., 2026, 62, 1229
DOI: 10.1039/D5CC06441D

Status and gaps toward fossil-free sustainable chemical production

Gabriele Centi and Siglinda Perathoner

Green Chem., 2022, 24, 7305
DOI: 10.1039/D2GC01572B

Highly selective electroreduction of nitrate to ammonia on a Ru-doped tetragonal Co2P monolayer with low-limiting overpotential

Jie Wu and Yang-Xin Yu

Catal. Sci. Technol., 2021, 11, 7160
DOI: 10.1039/D1CY01217G

Adsorption removal of Mn2+ and NH4+–N from electrolytic manganese metal wastewater by modified phosphate ore flotation tailings

Yuhao Wu, Jiancheng Shu, Wenxing Cao, Zihan Li, Bing Li, Zhonghui Xu, Hongliang Chen, Mengjun Chen and Zongyu Deng

Environ. Sci.: Water Res. Technol., 2023, 9, 125
DOI: 10.1039/D2EW00507G

Dinitrogen reduction to ammonia with a pincer-Mo complex: new insights into the mechanism of nitride-to-ammonia conversion

Souvik Mandal, Xiaoguang Zhou, Quinton J. Bruch, Rachel N. Allen, Laurence W. Giordano, Nicholas J. I. Walker, Thomas J. Emge, Faraj Hasanayn, Alexander J. M. Miller, Santanu Malakar and Alan S. Goldman

Chem. Sci., 2025, 16, 7347
DOI: 10.1039/D5SC00454C

Magnetron sputtering tuned “π back-donation” sites over metal oxides for enhanced electrocatalytic nitrogen reduction

Yuan Tian, Bin Chang, Guihua Wang, Lili Li, Lianguo Gong, Bo Wang, Rusheng Yuan and Weijia Zhou

J. Mater. Chem. A, 2022, 10, 2800
DOI: 10.1039/D1TA10273G

Reactivity of molybdenum–nitride complex bearing pyridine-based PNP-type pincer ligand toward carbon-centered electrophiles

Takayuki Itabashi, Kazuya Arashiba, Shogo Kuriyama and Yoshiaki Nishibayashi

Dalton Trans., 2022, 51, 1946
DOI: 10.1039/D1DT03952K

Advanced (photo)electrocatalytic approaches to substitute the use of fossil fuels in chemical production

Gabriele Centi, Siglinda Perathoner, Chiara Genovese and Rosa Arrigo

Chem. Commun., 2023, 59, 3005
DOI: 10.1039/D2CC05132J

Making chemicals from the air: the new frontier for hybrid electrosyntheses in artificial tree-like devices

Gabriele Centi and Siglinda Perathoner

Green Chem., 2024, 26, 15
DOI: 10.1039/D3GC02135A

Spontaneous N2-diboranylation of [W(N2)2(dppe)2] with B2Br4(SMe2)2

Lisa C. Haufe, Merle Arrowsmith, Maximilian Dietz, Annalena Gärtner, Rüdiger Bertermann and Holger Braunschweig

Dalton Trans., 2022, 51, 12786
DOI: 10.1039/D2DT02135H

Electrochemically synthesized SnO2 with tunable oxygen vacancies for efficient electrocatalytic nitrogen fixation

Xiaojia He, Haoran Guo, Tianhao Liao, Yi Pu, Long Lai, Zihao Wang and Hui Tang

Nanoscale, 2021, 13, 16307
DOI: 10.1039/D1NR04621G

Theoretical investigation of borane compounds mimicking transition metals for N2fixation and activation

Zhipeng Li, Guoliang Song and Zhen Hua Li

Phys. Chem. Chem. Phys., 2023, 25, 1331
DOI: 10.1039/D2CP04560E

Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N2)2(diphosphine)2 complexes

Charles H. Beasley, Olivia L. Duletski, Ksenia S. Stankevich, Navamoney Arulsamy and Michael T. Mock

Dalton Trans., 2024, 53, 6496
DOI: 10.1039/D4DT00702F

NiFeB-assisted adsorption and activation of nitrogen to improve the photooxidation activity of zinc porphyrin

Xuan Zhang, Yawen Tan, Juntao Zhao, Zixuan Cai, Jun Zhang and Puttaswamy Madhusudan

Chem. Commun., 2024, 60, 4298
DOI: 10.1039/D4CC00249K

Few-layer black phosphorus enables nitrogen fixation under ambient conditions

Francisco Garnes-Portolés, Vicent Lloret, José Alejandro Vidal-Moya, Mario Löffler, Karl J. J. Mayrhofer, Jose Pedro Cerón-Carrasco, Gonzalo Abellán and Antonio Leyva-Pérez

RSC Adv., 2024, 14, 4742
DOI: 10.1039/D3RA07331A

Two-fold proton coupled electron transfer of a Ta(v) aniline complex mediated by a redox active NNN pincer ligand

Sotirios Pavlidis, Jasmin Alasadi, Amanda Opis-Basilio and Josh Abbenseth

Dalton Trans., 2025, 54, 2421
DOI: 10.1039/D4DT03281K

(Plasmonic gold core)@(ultrathin ruthenium shell) nanostructures as antenna-reactor photocatalysts toward nitrogen photofixation

Henglei Jia, Yuanyuan Yang, Yanrong Dou, Fan Li, Mengxuan Zhao and Chun-yang Zhang

Chem. Commun., 2022, 58, 1013
DOI: 10.1039/D1CC06014G

Room temperature dinitrogen cleavage and hydrogenation with organometallic complexes of uranium

Angus C. G. Shephard, Lucie Pedussaut, Linda De Marchi, Luca Demonti, Thayalan Rajeshkumar, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Thomas Simler and Grégory Nocton

Chem. Sci., 2025, 16, 21334
DOI: 10.1039/D5SC07194A

Nitrogen fixation and transformation with main group elements

Tong-Tong Liu, Dan-Dan Zhai, Bing-Tao Guan and Zhang-Jie Shi

Chem. Soc. Rev., 2022, 51, 3846
DOI: 10.1039/D2CS00041E

An orbitally adapted push–pull template for N2 activation and reduction to diazene-diide

David Specklin, Marie-Christine Boegli, Anaïs Coffinet, Léon Escomel, Laure Vendier, Mary Grellier and Antoine Simonneau

Chem. Sci., 2023, 14, 14262
DOI: 10.1039/D3SC04390H

Modulation of BiOBr-based photocatalysts for energy and environmental application: A critical review

Guo-Qing Zhao, Jun Hu, Jiao Zou, Xuan Long and Fei-Peng Jiao

Journal of Environmental Chemical Engineering, 2022, 10, 107226
DOI: 10.1016/j.jece.2022.107226

Sustainable Carbon‐Based Catalyst Materials Derived From Lignocellulosic Biomass for Energy Storage and Conversion: Atomic Modulation and Properties Improvement

Wei Li, Ying Xu, Guanhua Wang, Ting Xu, Kui Wang, Shangru Zhai and Chuanling Si

Carbon Energy, 2025, 7
DOI: 10.1002/cey2.708

Increased Nitrogenase Activity in Solar‐Driven Biohybrids Containing Non‐photosynthetic Bacteria and Conducting Polymers

Yue Zeng, Haotian Bai, Wen Yu, Shengpeng Xia, Qi Shen, Yiming Huang, Fengting Lv, Guillermo C. Bazan and Shu Wang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202303877

From Dinitrogen to N‐Containing Organic Compounds: Using Li2CN2 as a Synthon

Li‐Jun Wu, Qianru Wang, Jianping Guo, Junnian Wei, Ping Chen and Zhenfeng Xi

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202219298

Chemocatalytic Conversion of Dinitrogen to Ammonia Mediated by a Tungsten Complex

Anna‐Marlene Vogt, Tobias A. Engesser, Jan Krahmer, Niels Michaelis, Mareike Pfeil, Jannik Junge, Christian Näther, Nicolas Le Poul and Felix Tuczek

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202420220

Seven‐Coordinate Group 6 Metal Hydrides Obtained by H2 Activation at B(C6F5)3 Adducts of N2 Complexes: Frustrated Lewis Pair‐Type Reactivity of The B−N Linkage

Marie‐Christine Boegli, Anaïs Coffinet, Christian Bijani and Antoine Simonneau

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400451

Spin Manipulation of Co sites in Co9S8/Nb2CTx Mott–Schottky Heterojunction for Boosting the Electrocatalytic Nitrogen Reduction Reaction

Shuai Zhang, Weihua Zhao, Jiameng Liu, Zheng Tao, Yinpeng Zhang, Shuangrun Zhao, Zhihong Zhang and Miao Du

Advanced Science, 2024, 11
DOI: 10.1002/advs.202407301

The synthesis and characterization of a bidentate complex of 1,1′-(1,3-phenylene)bis(3-butylimidazolium) pincer proligand with molybdenum – A non-pincer binding mode

Samuel D. Juárez-Escamilla, Sriloy Dey, Bruno Donnadieu and T. Keith Hollis

Polyhedron, 2024, 247, 116714
DOI: 10.1016/j.poly.2023.116714

Trisilylation of a Formal Cr(−I) Bis-dinitrogen Complex

Botao Wu, Wang Chen, Haihan Yan, Xinchao Zhang, Junnian Wei, Zhenfeng Xi, Gao-Xiang Wang and Shengfa Ye

J. Am. Chem. Soc., 2025, 147, 32480
DOI: 10.1021/jacs.5c05591

Mechanisms of Electrochemical N2 Splitting by a Molybdenum Pincer Complex

Quinton J. Bruch, Santanu Malakar, Alan S. Goldman and Alexander J. M. Miller

Inorg. Chem., 2022, 61, 2307
DOI: 10.1021/acs.inorgchem.1c03698

Vanadium-Catalyzed Dinitrogen Reduction to Ammonia via a [V]═NNH2 Intermediate

Wenshuang Huang, Ling-Ya Peng, Jiayu Zhang, Chenrui Liu, Guoyong Song, Ji-Hu Su, Wei-Hai Fang, Ganglong Cui and Shaowei Hu

J. Am. Chem. Soc., 2023, 145, 811
DOI: 10.1021/jacs.2c08000

A comparative study of the potential of [Os{(NHCH2CH2)3X}] catalysts (XN, P) for the reduction of dinitrogen to ammonia and hydrazine using FLP‐H2 as a co‐catalyst by density functional theory

Akhil K. Sivan and Chinnappan Sivasankar

Applied Organom Chemis, 2023, 37
DOI: 10.1002/aoc.7067

Sandwich-Structured Metal–Organic Framework/Polyoxometalate Nanocomposites for Photocatalytic Nitrogen Reduction under Visible Light

Xiaodong Liu, Xingwang Li, Jing Zhang, Yao Di, Xiaoshu Qu and Weilin Chen

ACS Appl. Nano Mater., 2025, 8, 15673
DOI: 10.1021/acsanm.5c02737

Catalytic Reduction of N2 to Borylamine at a Molybdenum Complex

Soukaina Bennaamane, Maria F. Espada, Andrea Mulas, Théo Personeni, Nathalie Saffon‐Merceron, Marie Fustier‐Boutignon, Christophe Bucher and Nicolas Mézailles

Angew Chem Int Ed, 2021, 60, 20210
DOI: 10.1002/anie.202106025

Dinitrogen Activation and Functionalization Affording Chromium Diazenido and Hydrazido Complexes

Gao-Xiang Wang, Zhu-Bao Yin, Junnian Wei and Zhenfeng Xi

Acc. Chem. Res., 2023, 56, 3211
DOI: 10.1021/acs.accounts.3c00476

NIR photothermal enhancement to achieve high-efficiency nitrogen reduction to ammonia by polyoxometalates@Fe-polydopamine

Xiaofei Chen, Lixin Wu and Feng Bai

Nano Research, 2025, 18, 94907006
DOI: 10.26599/NR.2025.94907006

Preparation and Reactivity of Anionic Iron Sandwich Complex Bearing π‐Phenol Ligand Acting as Proton‐Coupled Electron Transfer Reagent

Yoshiaki Tanabe, Soma Yamamoto, Shogo Kuriyama and Yoshiaki Nishibayashi

Chemistry An Asian Journal, 2026, 21
DOI: 10.1002/asia.202500951

Leveraging Quantum Chemistry and Machine Learning for the Design of Low-Valent Transition Metal Catalysts in Nitrogen to Ammonia Conversion

Chandrasekhar Nettem, Ankit Mondal and Gopalan Rajaraman

J. Am. Chem. Soc., 2025, 147, 16948
DOI: 10.1021/jacs.5c00099

Catalytic nitrogen fixation using visible light energy

Yuya Ashida, Yuto Onozuka, Kazuya Arashiba, Asuka Konomi, Hiromasa Tanaka, Shogo Kuriyama, Yasuomi Yamazaki, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-34984-1

Synthesis of Collidine from Dinitrogen via a Tungsten Nitride

Lukas Eberle and Joachim Ballmann

J. Am. Chem. Soc., 2024, 146, 7979
DOI: 10.1021/jacs.4c02226

Nitrogen Fixation by Manganese Complexes – Waiting for the Rush?

Quentin Le Dé, Dmitry A. Valyaev and Antoine Simonneau

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400784

Synthesis and Structural Characterization of Dinitrogen Chromium Complexes with Triamidoamine Ligands Possessing Bulky Substituents, and Nitrogen Fixation by These Complexes

Takeru Kuribayashi, Yoshiaki Kokubo, Haruki Nagai, Tomoya Furui, Tomohiro Ozawa, Hideki Masuda and Yuji Kajita

Inorganics, 2026, 14, 24
DOI: 10.3390/inorganics14010024

Synthesis, characterization of indol-2-yl-based NCO pincer rare-earth metal alkyl complexes and their catalytic activity towards hydroboration of imines

Xinlei Yi, Xian Ji, Zeming Huang, Fenhua Wang, Pinhua Li and Shaowu Wang

Journal of Organometallic Chemistry, 2024, 1015, 123215
DOI: 10.1016/j.jorganchem.2024.123215

Exploration of Multidimensional Structural Optimization and Regulation Mechanisms: Catalysts and Reaction Environments in Electrochemical Ammonia Synthesis

Kaibin Chu, Bo Weng, Zhaorui Lu, Yang Ding, Wei Zhang, Rui Tan, Yu‐Ming Zheng and Ning Han

Advanced Science, 2025, 12
DOI: 10.1002/advs.202416053

Molybdenum‐Catalyzed Ammonia Synthesis by Using Zero‐Valent Metal Powder with Alcohols or Water

Taichi Mitsumoto and Yoshiaki Nishibayashi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202423858

N2 Reduction versus H2 Evolution in a Molybdenum‐ or Tungsten‐Based Small‐Molecule Model System of Nitrogenase

Jannik Junge, Tobias A. Engesser and Felix Tuczek

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202202629

Overview of physiological, biochemical, and regulatory aspects of nitrogen fixation in Azotobacter vinelandii

Julia S. Martin del Campo, Jack Rigsbee, Marcelo Bueno Batista, Florence Mus, Luis M. Rubio, Oliver Einsle, John W. Peters, Ray Dixon, Dennis R. Dean and Patricia C. Dos Santos

Critical Reviews in Biochemistry and Molecular Biology, 2022, 57, 492
DOI: 10.1080/10409238.2023.2181309

Coordination Structure of Samarium Diiodide in a Tetrahydrofuran–Water Mixture

Akira Yamamoto, Xueshi Liu, Kazuya Arashiba, Asuka Konomi, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi and Hisao Yoshida

Inorg. Chem., 2023, 62, 5348
DOI: 10.1021/acs.inorgchem.2c03752

Unusual Electronic Structures of an Electron Transfer Series of [Cr(μ‐η1 : η1‐N2)Cr]0/1+/2+

Gao‐Xiang Wang, Chunxiao Shan, Wang Chen, Botao Wu, Peng Zhang, Junnian Wei, Zhenfeng Xi and Shengfa Ye

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202315386

Preparation and Reactivity of Rhenium–Nitride Complexes Bearing PNP-Type Pincer Ligands toward Nitrogen Fixation

Fanqiang Meng, Shogo Kuriyama, Akihito Egi, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Organometallics, 2023, 42, 1065
DOI: 10.1021/acs.organomet.2c00312

Snapshots of Early-Stage Quantitative N2 Electrophilic Functionalization

Gao-Xiang Wang, Xueli Wang, Yang Jiang, Wang Chen, Chunxiao Shan, Peng Zhang, Junnian Wei, Shengfa Ye and Zhenfeng Xi

J. Am. Chem. Soc., 2023, 145, 9746
DOI: 10.1021/jacs.3c01497

Mechanism-Driven Design of Catalytic N2 Fixation Mediated by Copper Carbenes: From DFT Insights to a Descriptor-Based Predictive Model

Weichi Chen, Jinxia Li and Shuanglin Qu

Organometallics, 2026
DOI: 10.1021/acs.organomet.6c00060

Enhancing electrochemical nitrogen fixation by mimicking π back-donation on laser-tuned Lewis acid sites in noble-metal-molybdenum carbide

Bin Chang, Haifeng Yuan, Lili Li, Jiayuan Yu, Xiaoyu Liu, Wanqiang Yu, Bo Wang, Lili Zhao, Xiaoyan Liu, Shuhui Sun, Hong Liu and Weijia Zhou

Applied Catalysis B: Environmental, 2023, 320, 121777
DOI: 10.1016/j.apcatb.2022.121777

Catalytic Nitrogen Fixation Using Well‐Defined Molecular Catalysts under Ambient or Mild Reaction Conditions

Yoshiaki Tanabe and Yoshiaki Nishibayashi

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202406404

Syntheses, Characterizations, Crystal Structures, and Protonation Reactions of Dinitrogen Chromium Complexes Supported with Triamidoamine Ligands

Yoshiaki Kokubo, Kazuki Tsuzuki, Hikari Sugiura, Shunsuke Yomura, Yuko Wasada-Tsutsui, Tomohiro Ozawa, Sachiko Yanagisawa, Minoru Kubo, Tomoyuki Takeyama, Takahide Yamaguchi, Yuichi Shimazaki, Shinichi Kugimiya, Hideki Masuda and Yuji Kajita

Inorg. Chem., 2023, 62, 5320
DOI: 10.1021/acs.inorgchem.2c01561

Dispersing Au nanoclusters on porphyrin-based metal-organic framework photocatalyst for enhanced proton supply to the Fe–N–N * sites in N2 fixation

Qibing Dong, Ximing Li, Yanyan Duan, Xue He, Xinxin Liang, Feng Yu and Chuanyi Wang

Applied Catalysis B: Environment and Energy, 2025, 366, 125042
DOI: 10.1016/j.apcatb.2025.125042

Hydroboration and Hydrosilylation of a Molybdenum–Nitride Complex Bearing a PNP-Type Pincer Ligand

Takayuki Itabashi, Kazuya Arashiba, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Organometallics, 2022, 41, 366
DOI: 10.1021/acs.organomet.1c00597

Mechanochemical Synthesis of Ammonia Employing H2O as the Proton Source Under Room Temperature and Atmospheric Pressure

Chengli He, Qiaodan Li, Xiaoyan Zhang, Yuxuan Lu, Dong Qiu, Yang Chen and Xiaoli Cui

ACS Sustainable Chem. Eng., 2022, 10, 746
DOI: 10.1021/acssuschemeng.1c05643

Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN3P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism

Katja Bedbur, Nadja Stucke, Lina Liehrs, Jan Krahmer and Felix Tuczek

Molecules, 2022, 27, 7843
DOI: 10.3390/molecules27227843

From Dinitrogen to N‐Containing Organic Compounds: Using Li2CN2 as a Synthon

Li‐Jun Wu, Qianru Wang, Jianping Guo, Junnian Wei, Ping Chen and Zhenfeng Xi

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202219298

Recent advances in catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

Yoshiaki Tanabe and Yoshiaki Nishibayashi

Coordination Chemistry Reviews, 2022, 472, 214783
DOI: 10.1016/j.ccr.2022.214783

Mechanistic Insights into the Reductive N–O Bond Cleavage of O-Acyl Hydroxylamines: Dual Reactivity as Potent Oxidants and Nitrogen Transfer Agents

Parul Bishnoi, Arya Singh, Yashdeep Maurya, Vineet Jhamb, Akhilesh Sharma, Swetha Vasanthdamodar Sivapreetha and Sayanti Chatterjee

ACS Org. Inorg. Au, 2025, 5, 385
DOI: 10.1021/acsorginorgau.5c00063

A Broad Light‐Harvesting Conjugated Oligoelectrolyte Enables Photocatalytic Nitrogen Fixation in a Bacterial Biohybrid

Zhongxin Chen, Glenn Quek, Ji‐Yu Zhu, Samuel J. W. Chan, Sarah J. Cox‐Vázquez, Fernando Lopez‐Garcia and Guillermo C. Bazan

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202307101

Catalytic ammonia formation from dinitrogen, water, and visible light energy

Yasuomi Yamazaki, Yoshiki Endo and Yoshiaki Nishibayashi

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-59727-w

Increased Nitrogenase Activity in Solar‐Driven Biohybrids Containing Non‐photosynthetic Bacteria and Conducting Polymers

Yue Zeng, Haotian Bai, Wen Yu, Shengpeng Xia, Qi Shen, Yiming Huang, Fengting Lv, Guillermo C. Bazan and Shu Wang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202303877

Emerging Chemical Diversity and Potential Applications of Enzymes in the DMSO Reductase Superfamily

Chi (Chip) Le, Minwoo Bae, Sina Kiamehr and Emily P. Balskus

Annu. Rev. Biochem., 2022, 91, 475
DOI: 10.1146/annurev-biochem-032620-110804

Mechanism of Nitrogen-Carbon Bond Formation from Iron(IV) Disilylhydrazido Intermediates during N2Reduction

Samuel M. Bhutto, Reagan X. Hooper, Brandon Q. Mercado and Patrick L. Holland

J. Am. Chem. Soc., 2023, 145, 4626
DOI: 10.1021/jacs.2c12382

Electrocatalytic Reduction of Nitrogen to Ammonia Using Tiara‐like Phenylethanethiolated Nickel Cluster

Manju P. Maman, Tamilselvi Gurusamy, Arun K. Pal, Rajkumar Jana, Kothandaraman Ramanujam, Ayan Datta and Sukhendu Mandal

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305462

Catalytic Reduction of Dinitrogen via Hydroboration

Shun Suginome, Atsushi Okochi, Taiji Nakamura, Asuka Konomi, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

J. Am. Chem. Soc., 2025, 147, 26684
DOI: 10.1021/jacs.5c07294

Catalytic Nitrogen Fixation Using Well‐Defined Molecular Catalysts under Ambient or Mild Reaction Conditions

Yoshiaki Tanabe and Yoshiaki Nishibayashi

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202406404

An Experimental and Computational Investigation Rules Out Direct Nucleophilic Addition on the N2 Ligand in Manganese Dinitrogen Complex [Cp(CO)2Mn(N2)]

Quentin Le Dé, Amal Bouammali, Christian Bijani, Laure Vendier, Iker del Rosal, Dmitry A. Valyaev, Chiara Dinoi and Antoine Simonneau

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305235

Mechanochemical nitrogen fixation catalysed by molybdenum complexes

Shun Suginome, Kurumi Murota, Akira Yamamoto, Hisao Yoshida and Yoshiaki Nishibayashi

Nat. Synth, 2024, 4, 243
DOI: 10.1038/s44160-024-00661-y

Recent Progress on Fullerene–Based Functional Materials for Energy Conversion

Ying Jiang, Bo Wu and Chunru Wang

Carbon Energy, 2026
DOI: 10.1002/cey2.70182

Synthesis and Reactivity of Cobalt–Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen

Shogo Kuriyama, Shenglan Wei, Hiromasa Tanaka, Asuka Konomi, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Inorg. Chem., 2022, 61, 5190
DOI: 10.1021/acs.inorgchem.2c00234

Side-On N2 Binding and Reduction by a Heterotetrametallic Zr2Co2 Cluster

Adwitiya Singh, Curtis E. Moore and Christine M. Thomas

J. Am. Chem. Soc., 2025, 147, 40087
DOI: 10.1021/jacs.5c14342

Ammonia Formation Catalyzed by a Dinitrogen‐Bridged Dirhenium Complex Bearing PNP‐Pincer Ligands under Mild Reaction Conditions**

Fanqiang Meng, Shogo Kuriyama, Hiromasa Tanaka, Akihito Egi, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angew Chem Int Ed, 2021, 60, 13906
DOI: 10.1002/anie.202102175

Catalytic Reduction of N2 to Borylamine at a Molybdenum Complex

Soukaina Bennaamane, Maria F. Espada, Andrea Mulas, Théo Personeni, Nathalie Saffon‐Merceron, Marie Fustier‐Boutignon, Christophe Bucher and Nicolas Mézailles

Angewandte Chemie, 2021, 133, 20372
DOI: 10.1002/ange.202106025

Catalytic Reduction of Dinitrogen into Ammonia and Hydrazine by Using Chromium Complexes Bearing PCP‐Type Pincer Ligands**

Yuya Ashida, Akihito Egi, Kazuya Arashiba, Hiromasa Tanaka, Taichi Mitsumoto, Shogo Kuriyama, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202200557

Unveiling Unusual Reactivity of SO2 and Unusual Type of S–X Long Bonds

Shuai Ma, Longfei Li, Xiaofeng Xie, Peng Wang, He Bai, Kan Yang, Xueqing Song and Henry F. Schaefer

Inorg. Chem., 2025, 64, 14684
DOI: 10.1021/acs.inorgchem.5c02435

Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation

Shogo Kuriyama, Shenglan Wei, Takeru Kato and Yoshiaki Nishibayashi

Molecules, 2022, 27, 2373
DOI: 10.3390/molecules27072373

Structural comparison of (hyper‐)thermophilic nitrogenase reductases from three marine Methanococcales

Nevena Maslać, Cécile Cadoux, Pauline Bolte, Fenja Murken, Wenyu Gu, Ross D. Milton and Tristan Wagner

The FEBS Journal, 2024, 291, 3454
DOI: 10.1111/febs.17148

Nitrogen reduction by the Fe sites of synthetic [Mo3S4Fe] cubes

Yasuhiro Ohki, Kenichiro Munakata, Yuto Matsuoka, Ryota Hara, Mami Kachi, Keisuke Uchida, Mizuki Tada, Roger E. Cramer, W. M. C. Sameera, Tsutomu Takayama, Yoichi Sakai, Shogo Kuriyama, Yoshiaki Nishibayashi and Kazuki Tanifuji

Nature, 2022, 607, 86
DOI: 10.1038/s41586-022-04848-1

Dinitrogen activation and transformation by multimetallic polyhydride complexes

Takanori Shima, Qingde Zhuo and Zhaomin Hou

Coordination Chemistry Reviews, 2022, 472, 214766
DOI: 10.1016/j.ccr.2022.214766

Activation of Dinitrogen Promoted by Adsorption of C6H6 on Fe2VC– Cluster Anions

Xin Cheng, Zi-Yu Li, Gui-Duo Jiang, Xiao-Xiao Liu, Qing-Yu Liu and Sheng-Gui He

J. Phys. Chem. Lett., 2023, 14, 6431
DOI: 10.1021/acs.jpclett.3c01367

Benchmark Study of Density Functional Theory Methods in Geometry Optimization of Transition Metal–Dinitrogen Complexes

Chaoyue Zhao, Rongkai Wu, Shuoqing Zhang and Xin Hong

J. Phys. Chem. A, 2023, 127, 6791
DOI: 10.1021/acs.jpca.3c04215

Catalytic Nitrogen Fixation Using Molybdenum–Oxo Complexes Bearing NHC-Based PCP-Type Pincer Ligands Via Oxo-to-Nitride Conversion

Yoshikatsu Kameda, Shun Suginome, Taiji Nakamura, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

J. Am. Chem. Soc., 2026, 148, 8884
DOI: 10.1021/jacs.5c21715

Electronic Structure and Ligand Effects on the Activation and Cleavage of N2 on a Molybdenum Center

Maria V. White, Emily E. Claveau, Evangelos Miliordos and Konstantinos D. Vogiatzis

J. Phys. Chem. A, 2024, 128, 2038
DOI: 10.1021/acs.jpca.3c07801

Dinitrogen Activation and Cyanide Release by the Gas-Phase Cluster Anions InNbC2–: Synergistic Effects of the p-Block Indium and the d-Block Niobium

Xiao-Wang Li, Feng-Xiang Zhang, Xi-Guan Zhao, Qing-Yu Liu, Sheng-Gui He and Jia-Bi Ma

J. Am. Chem. Soc., 2025, 147, 22185
DOI: 10.1021/jacs.5c06920

Dinitrogen Activation Mediated by the (P2PPh)Fe Complex: Electronic Structure, Dimerization Mechanism, and Magnetic Coupling

Jhon Zapata-Rivera and Carmen J. Calzado

Inorg. Chem., 2024, 63, 1633
DOI: 10.1021/acs.inorgchem.3c03813

Iron(I) Complex Bearing an Open-Shell Diazenido Ligand

Qing Liu, Peng Wang, Yujian Wang, Junjie Zou, Xuebing Leng and Liang Deng

J. Am. Chem. Soc., 2024, 146, 13629
DOI: 10.1021/jacs.4c03483

Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex

Naofumi Suzuki, Yutaka Ishida and Hiroyuki Kawaguchi

Molecules, 2022, 27, 5553
DOI: 10.3390/molecules27175553

Construction of Carbazoles from 2‐Bromobiaryls Using N2 as a N Source

Kai Wang, Chang‐Cheng Wang, Yang Liao, Feng Liu, Dan‐Dan Zhai and Zhang‐Jie Shi

Chin. J. Chem., 2026, 44, 1573
DOI: 10.1002/cjoc.70502

Constructing oxygen vacancies and linker defects in MIL-125 @TiO2 for efficient photocatalytic nitrogen fixation

Libo Wang, Shiyu Wang, Mohan Li, Xue Yang, Fengyan Li, Lin Xu and Yongcun Zou

Journal of Alloys and Compounds, 2022, 909, 164751
DOI: 10.1016/j.jallcom.2022.164751

Mono(Silylene)‐Stabilized Borylenes for Small Molecule Activation

Ashim Tamuli and Ashwini K. Phukan

Chemistry A European J, 2026, 32
DOI: 10.1002/chem.202503449

Catalytic production of ammonia from dinitrogen employing molybdenum complexes bearing N-heterocyclic carbene-based PCP-type pincer ligands

Yuya Ashida, Takuro Mizushima, Kazuya Arashiba, Akihito Egi, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Nat. Synth, 2023, 2, 635
DOI: 10.1038/s44160-023-00292-9

Synthesis and Catalytic Activity of Molybdenum Complexes Bearing Dihydroimidazole‐Based PCP‐Type Pincer Ligands Toward Nitrogen Fixation

Yasuomi Yamazaki, Kaito Nakaya, Hiroki Otsuka, Taiji Nakamura, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

ChemistryEurope, 2026, 4
DOI: 10.1002/ceur.202500494

A Broad Light‐Harvesting Conjugated Oligoelectrolyte Enables Photocatalytic Nitrogen Fixation in a Bacterial Biohybrid

Zhongxin Chen, Glenn Quek, Ji‐Yu Zhu, Samuel J. W. Chan, Sarah J. Cox‐Vázquez, Fernando Lopez‐Garcia and Guillermo C. Bazan

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202307101

Electrocatalytic Reduction of Nitrogen to Ammonia Using Tiara‐like Phenylethanethiolated Nickel Cluster

Manju P. Maman, Tamilselvi Gurusamy, Arun K. Pal, Rajkumar Jana, Kothandaraman Ramanujam, Ayan Datta and Sukhendu Mandal

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305462

Dinitrogen Binding and Silylation by Bis(ketimino)carbazolide Complexes of Iron and Cobalt

Jack H. Lin, Alexis K. Bauer, Samuel T. Hugie, Michael L. Neidig and Datong Song

Inorg. Chem., 2025, 64, 14566
DOI: 10.1021/acs.inorgchem.5c02069

Enhancing Electrochemical Nitrogen Fixation by Mimicking Π Back-Donation on Laser-Tuned Lewis Acid Sites in Noble-Metal-Molybdenum Carbide

Bin Chang, Haifeng Yuan, Lili Li, Jiayuan Yu, Xiaoyu Liu, Wanqiang Yu, Bo Wang, Lili Zhao, Xiaoyan Liu, Shuhui Sun, Hong Liu and Weijia Zhou

SSRN Journal, 2022
DOI: 10.2139/ssrn.4102520

Advancements in Electrocatalytic Nitrogen Reduction Reaction: A Review on the Role of Catalyst Electronic Structure and Design Strategies

Wei Tan, Hongbo Zhao, Longhua Ding, Na Ren, Xin Yu, Aizhu Wang and Mingwen Zhao

ACS Appl. Nano Mater., 2025, 8, 2632
DOI: 10.1021/acsanm.4c05946

Engineered Geobacter sulfurreducens Achieves a Record-High Rate of Biological Nitrogen Fixation

Wei Yang, Xianyue Jing, Shuyao Lai, Hui Wang, Jun Wang, Xing Liu and Shungui Zhou

Environ. Sci. Technol., 2025, 59, 18605
DOI: 10.1021/acs.est.5c05266

Electrides with Tunable Electron Delocalization for Applications in Quantum Computing and Catalysis

Andrei Evdokimov, Valentina Nesterova, Marcelo A. Kuroda, Konstantin Klyukin and Evangelos Miliordos

ACS Materials Lett., 2025, 7, 3604
DOI: 10.1021/acsmaterialslett.5c00756

Unusual Electronic Structures of an Electron Transfer Series of [Cr(μ‐η1 : η1‐N2)Cr]0/1+/2+

Gao‐Xiang Wang, Chunxiao Shan, Wang Chen, Botao Wu, Peng Zhang, Junnian Wei, Zhenfeng Xi and Shengfa Ye

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202315386

Synthesis of Bis(silylene) Iron Chlorides and Their Catalytic Activity for Dinitrogen Silylation

Wenjing Yang, Xiaomiao Li, Sheng-Yong Li, Qingshuang Li, Hongjian Sun and Xiaoyan Li

Inorg. Chem., 2023, 62, 21014
DOI: 10.1021/acs.inorgchem.3c02445

Copper-based electro-catalytic nitrate reduction to ammonia from water: Mechanism, preparation, and research directions

Jinshan Wei, Yi Li, Hexing Lin, Xihui Lu, Chucheng Zhou and Ya-yun Li

Environmental Science and Ecotechnology, 2024, 20, 100383
DOI: 10.1016/j.ese.2023.100383

Reductive N2 Cleavage and Nitride Insertion Reactivity at Molybdenum Complexes Supported by a Rigid PNP Pincer

Minjun Kim, Jeewhan Oh, Sanha Park, Hankyul Lee, Zee Hwan Kim, Jin Kim, Heui Beom Lee, Jonghoon Choi and Yunho Lee

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202511887

Efficient photoelectrocatalytic ammonia synthesis over graphene oxide-modified Fe-based metal-organic frameworks with high conductivity and photoresponsivity

Rong Gao, Xiaosong Wang, Guilan Fan, Yan Guo, Shoujun Guo, Chenhui Han, Junfang Ding, Yuliang Gao and Xiaojun Gu

Journal of Colloid and Interface Science, 2026, 708, 139799
DOI: 10.1016/j.jcis.2025.139799

Isocyanide Ligation Enables Electrochemical Ammonia Formation in a Synthetic Cycle for N2 Fixation

Jeremy E. Weber, Noah D. McMillion, Alexander S. Hegg, Ashlee E. Wertz, Mehrnaz Aliahmadi, Brandon Q. Mercado, Robert H. Crabtree, Hannah S. Shafaat, Alexander J. M. Miller and Patrick L. Holland

J. Am. Chem. Soc., 2024, 146, 33595
DOI: 10.1021/jacs.4c11187

Ammonia Synthesis at Room Temperature and Atmospheric Pressure from N2: A Boron‐Radical Approach

Soukaina Bennaamane, Barbara Rialland, Lhoussain Khrouz, Marie Fustier‐Boutignon, Christophe Bucher, Eric Clot and Nicolas Mézailles

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202209102

Chemokatalytische Umwandlung von Distickstoff zu Ammoniak vermittelt durch einen Wolframkomplex

Anna‐Marlene Vogt, Tobias A. Engesser, Jan Krahmer, Niels Michaelis, Mareike Pfeil, Jannik Junge, Christian Näther, Nicolas Le Poul and Felix Tuczek

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202420220

Frontiers in Polyoxometalate‐Based Hybrids for Photothermal Catalysis

Xiaofei Chen, Qianqian Li, Meijie Li, Mingjin Shi, Minqiao Liang, Yifa Chen, Feng Bai and Ya‐Qian Lan

Adv Funct Materials, 2026, 36
DOI: 10.1002/adfm.202510863

Plasma Conversion of C, N2 and H2O into HCN and CO at Atmospheric Pressure and Near Ambient Temperature: Towards Oxamide Fertilisers?

Matteo Molteni, Tirtha Raj Acharya, Bethany Mulholland‐Prescott, Thomas Clayton, Deborah Kays, Peter Licence, Mike Sutton, Gary Walker, Elmar Slikboer, Stephen Otieno, Andreas Weilhard, Emerson Kohlrausch, David Robinson, Joseph Wright and Simon Woodward

ChemistryEurope, 2026, 4
DOI: 10.1002/ceur.202500320

Synthesis of Molybdenum Complexes Bearing Pyridine-Based PNP-Type Pincer Ligands with Pendent Pyridyl Unit and Their Catalytic Activity for Ammonia Formation

Yasuomi Yamazaki, Kaito Nakaya and Yoshiaki Nishibayashi

Organometallics, 2024, 43, 2747
DOI: 10.1021/acs.organomet.4c00290

Molybdenum‐Mediated N2‐Splitting and Functionalization in the Presence of a Coordinated Alkyne

Hannah K. Wagner, Hubert Wadepohl and Joachim Ballmann

Angew Chem Int Ed, 2021, 60, 25804
DOI: 10.1002/anie.202111325

Progress of Experimental and Computational Catalyst Design for Electrochemical Nitrogen Fixation

Zhe Chen, Chunli Liu, Licheng Sun and Tao Wang

ACS Catal., 2022, 12, 8936
DOI: 10.1021/acscatal.2c02629

Revolutionizing nitrogen and carbon dioxide fixation through advanced electrocatalytic strategies

Drishti Khandelwal, Kumar Rakesh Ranjan and Vivek Mishra

Sustainable Materials and Technologies, 2025, 44, e01370
DOI: 10.1016/j.susmat.2025.e01370

Harnessing Chromium(V) Hydrazido Intermediates for N2 Functionalization to Multisubstituted Hydrazines through Ligand Migration

Xueli Wang, Yue Wu, Yixi Wang, Rong Sun, Junnian Wei and Zhenfeng Xi

J. Am. Chem. Soc., 2025, 147, 35413
DOI: 10.1021/jacs.5c09083

Electrochemical reduction of N2 in mild conditions using redox or chemical catalysis: towards alternatives to the Haber-Bosch process?

Théo Personeni, Malo Duquesnoy, Christophe Bucher and Nicolas Mézailles

Coordination Chemistry Reviews, 2026, 557, 217726
DOI: 10.1016/j.ccr.2026.217726

Reductive N2 Cleavage and Nitride Insertion Reactivity at Molybdenum Complexes Supported by a Rigid PNP Pincer

Minjun Kim, Jeewhan Oh, Sanha Park, Hankyul Lee, Zee Hwan Kim, Jin Kim, Heui Beom Lee, Jonghoon Choi and Yunho Lee

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202511887

Energy- and atom-efficient chemical synthesis with endergonic photocatalysis

Huaiju Wang, Ya-Ming Tian and Burkhard König

Nat Rev Chem, 2022, 6, 745
DOI: 10.1038/s41570-022-00421-6

Prospects for Forming C–N Bonds from Dinitrogen

Nereida Hidalgo, Ryan Walser-Kuntz and Patrick L. Holland

ACS Catal., 2025, 15, 17478
DOI: 10.1021/acscatal.5c05366

Molybdenum‐Catalyzed Ammonia Synthesis by Using Zero‐Valent Metal Powder with Alcohols or Water

Taichi Mitsumoto and Yoshiaki Nishibayashi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202423858

Catalytic and stoichiometric stepwise conversion of side-on bound dinitrogen to ammonia mediated by a uranium complex

Mikhail S. Batov, Heather T. Partlow, Lucile Chatelain, John A. Seed, Rosario Scopelliti, Ivica Zivkovic, Ralph W. Adams, Stephen T. Liddle and Marinella Mazzanti

Nat. Chem., 2025, 17, 1425
DOI: 10.1038/s41557-025-01867-z

An Experimental and Computational Investigation Rules Out Direct Nucleophilic Addition on the N2 Ligand in Manganese Dinitrogen Complex [Cp(CO)2Mn(N2)]

Quentin Le Dé, Amal Bouammali, Christian Bijani, Laure Vendier, Iker del Rosal, Dmitry A. Valyaev, Chiara Dinoi and Antoine Simonneau

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305235

Molybdän‐vermittelte N2‐Spaltung und Funktionalisierung in Gegenwart eines koordinierten Alkins

Hannah K. Wagner, Hubert Wadepohl and Joachim Ballmann

Angewandte Chemie, 2021, 133, 26008
DOI: 10.1002/ange.202111325

Direct Synthesis of Organonitrogen Compounds from Dinitrogen Using Transition Metal Complexes: Leap from Stoichiometric Reactions to Catalytic Reactions

Shun Suginome and Yoshiaki Nishibayashi

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300850

Cooperative Ammonia Formation Catalyzed by Molybdenum and Samarium Complexes

Taichi Mitsumoto, Taiji Nakamura, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202507061

Photocatalytic vs. photosynthetic reduction of nitrogen into ammonia: The importance of the sacrificial reducing agent

Doha Zidouhia, Etienne Grau and Dario M. Bassani

Coordination Chemistry Reviews, 2026, 562, 217875
DOI: 10.1016/j.ccr.2026.217875

Potential of MXene-Based Heterostructures for Energy Conversion and Storage

Jinbo Pang, Bin Chang, Hong Liu and Weijia Zhou

ACS Energy Lett., 2022, 7, 78
DOI: 10.1021/acsenergylett.1c02132

Carbon dots-boosted active hydrogen for efficient electrocatalytic reduction of nitrate to ammonia

Dongxu Zhang, Yanhong Liu, Di Li, Tianyao Jiang, Qitao Chen, Chunliang Mao, Longhua Li, Deli Jiang and Baodong Mao

Journal of Alloys and Compounds, 2025, 1014, 178694
DOI: 10.1016/j.jallcom.2025.178694

Ammonia Formation Catalyzed by a Dinitrogen‐Bridged Dirhenium Complex Bearing PNP‐Pincer Ligands under Mild Reaction Conditions**

Fanqiang Meng, Shogo Kuriyama, Hiromasa Tanaka, Akihito Egi, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angewandte Chemie, 2021, 133, 14025
DOI: 10.1002/ange.202102175

A Cationic Pt(II) Dinitrogen Adduct: Synthesis and Characterization of a CCC-aNHC Pincer Pt Complex with Abnormal N-Heterocyclic Carbene Donor Arms

Evans Fosu, Nghia Le, Taofiq Abdulraheem, Bruno Donnadieu, Amanda L. Patrick, Charles Edwin Webster and T. Keith Hollis

Organometallics, 2024, 43, 467
DOI: 10.1021/acs.organomet.3c00411

Nitrogen Fixation Catalyzed by Well-Defined Molecular Catalysts

Yoshiaki Tanabe and Yoshiaki Nishibayashi

Bull. Jpn. Soc. Coord. Chem., 2026, 86, 15
DOI: 10.4019/bjscc.86.15

Constructing Mimic-Enzyme Catalyst: Polyoxometalates Regulating Carrier Dynamics of Metal–Organic Frameworks to Promote Photocatalytic Nitrogen Fixation

Xiao-Hong Li, Hui Li, Shen-Long Jiang, Lan Yang, Hui-Yi Li, Qi-Long Liu, Wei Bai, Qun Zhang, Chong Xiao and Yi Xie

ACS Catal., 2023, 13, 7189
DOI: 10.1021/acscatal.3c00944

Ammonia Synthesis at Room Temperature and Atmospheric Pressure from N2: A Boron‐Radical Approach

Soukaina Bennaamane, Barbara Rialland, Lhoussain Khrouz, Marie Fustier‐Boutignon, Christophe Bucher, Eric Clot and Nicolas Mézailles

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202209102

Investigating N2 Fixation Using a Bulky Fe(bisphosphine)2 Framework

Andrew D. Crawford, Laurence R. Doyle, Samuel J. Horsewill, William K. Myers, Daniel J. Scott and Andrew E. Ashley

Chemistry A European J, 2026, 32
DOI: 10.1002/chem.202502688

Enabling Molecular-Level Computational Description of Redox and Proton-Coupled Electron Transfer Reactions of Samarium Diiodide

Jonas Himmelstrup and Vidar R. Jensen

J. Phys. Chem. A, 2023, 127, 3796
DOI: 10.1021/acs.jpca.3c00418

Toward Next-Generation Semiartificial Photosynthesis: Multidisciplinary Engineering of Biohybrid Systems

Jie Ye, Wenzhi Gu, Jing Hu, Li Chen, Chaohui Yang, Jiangtao Gao and Shungui Zhou

Chem. Rev., 2025, 125, 12198
DOI: 10.1021/acs.chemrev.5c00658

Cooperative Ammonia Formation Catalyzed by Molybdenum and Samarium Complexes

Taichi Mitsumoto, Taiji Nakamura, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202507061

Cyclometalated Iron(II) Thiolate Complexes Featuring Diazine Rings: π-Acceptor Character of the C,N-Chelate Moiety

Ryota Futaki, Noriko Chikaraishi Kasuga and Masakazu Hirotsu

Inorg. Chem., 2025, 64, 23225
DOI: 10.1021/acs.inorgchem.5c03689

Efficient catalyst-free N2 fixation by water radical cations under ambient conditions

Xiaoping Zhang, Rui Su, Jingling Li, Liping Huang, Wenwen Yang, Konstantin Chingin, Roman Balabin, Jingjing Wang, Xinglei Zhang, Weifeng Zhu, Keke Huang, Shouhua Feng and Huanwen Chen

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-45832-9