Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry

Timothy A. Shuttleworth, Miguel A. Huertos, Indrek Pernik, Rowan D. Young and Andrew S. Weller

Dalton Trans., 2013, 42, 12917
DOI: 10.1039/c3dt50817j

Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

Naomi E. Stubbs, Titel Jurca, Erin M. Leitao, Christopher H. Woodall and Ian Manners

Chem. Commun., 2013, 49, 9098
DOI: 10.1039/c3cc44373f

Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

Thomas N. Hooper, Andrew S. Weller, Nicholas A. Beattie and Stuart A. Macgregor

Chem. Sci., 2016, 7, 2414
DOI: 10.1039/C5SC04150C

Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]+

Heather C. Johnson, Rebecca Torry-Harris, Laura Ortega, Robin Theron, J. Scott McIndoe and Andrew S. Weller

Catal. Sci. Technol., 2014, 4, 3486
DOI: 10.1039/C4CY00597J

Organometallic chemistry using partially fluorinated benzenes

Sebastian D. Pike, Mark R. Crimmin and Adrian B. Chaplin

Chem. Commun., 2017, 53, 3615
DOI: 10.1039/C6CC09575E

Revealing the P–B coupling event in the rhodium catalysed dehydrocoupling of phosphine–boranes H3B·PR2H (R = tBu, Ph)

Miguel A. Huertos and Andrew S. Weller

Chem. Sci., 2013, 4, 1881
DOI: 10.1039/c3sc50122a

Formation of an iron phosphine–borane complex by formal insertion of BH3 into the Fe–P bond

Nicolas Frank, Katharina Hanau, Kimon Flosdorf and Robert Langer

Dalton Trans., 2013, 42, 11252
DOI: 10.1039/c3dt51254a

Oxidation of Substituted Phosphanylboranes with Chalcogens

Christian Marquardt, Oliver Hegen, Tobias Kahoun and Manfred Scheer

Chemistry A European J, 2017, 23, 4397
DOI: 10.1002/chem.201605625

On the Brink of Decomposition: Controlled Oxidation of a Substituted Arsanylborane as a Way to Labile Group 13‐15‐16 Compounds

Felix Lehnfeld, Michael Seidl, Alexey Y. Timoshkin and Manfred Scheer

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202300338

Reactivity of Ru(II) and V(III) complexes of diazafluorene derivatives towards B–H bonds

Trevor Janes, Vincent T. Annibale and Datong Song

Journal of Organometallic Chemistry, 2018, 872, 79
DOI: 10.1016/j.jorganchem.2018.07.025

High Molar Mass Poly(alkylphosphinoboranes) via Iron-Catalyzed Dehydropolymerization

Diego A. Resendiz-Lara, Vincent T. Annibale, Alastair W. Knights, Saurabh S. Chitnis and Ian Manners

Macromolecules, 2021, 54, 71
DOI: 10.1021/acs.macromol.0c02082

Metallfreie Additions‐/Kopf‐Schwanz‐Polymerisation von intermediär gebildeten Phosphanylboranen, RPH‐BH2: ein Weg zu Poly(alkylphosphanylboranen)

Christian Marquardt, Titel Jurca, Karl‐Christian Schwan, Andreas Stauber, Alexander V. Virovets, George R. Whittell, Ian Manners and Manfred Scheer

Angewandte Chemie, 2015, 127, 13986
DOI: 10.1002/ange.201507084

Paramagnetic Titanium(III) and Zirconium(III) Metallocene Complexes as Precatalysts for the Dehydrocoupling/Dehydrogenation of Amine–Boranes

Holger Helten, Barnali Dutta, James R. Vance, Matthew E. Sloan, Mairi F. Haddow, Stephen Sproules, David Collison, George R. Whittell, Guy C. Lloyd‐Jones and Ian Manners

Angew Chem Int Ed, 2013, 52, 437
DOI: 10.1002/anie.201207903

Iron‐Catalyzed Dehydropolymerization: A Convenient Route to Poly(phosphinoboranes) with Molecular‐Weight Control

André Schäfer, Titel Jurca, Joshua Turner, James R. Vance, Kajin Lee, Van An Du, Mairi F. Haddow, George R. Whittell and Ian Manners

Angew Chem Int Ed, 2015, 54, 4836
DOI: 10.1002/anie.201411957

A Convenient Route to Monoalkyl‐Substituted Phosphanylboranes (HRP–BH2–NMe3): Prospective Precursors to Poly[(alkylphosphino)boranes]

Andreas Stauber, Titel Jurca, Christian Marquardt, Martin Fleischmann, Michael Seidl, George R. Whittell, Ian Manners and Manfred Scheer

Eur J Inorg Chem, 2016, 2016, 2684
DOI: 10.1002/ejic.201600226

Depolymerization of Poly(phosphinoboranes): From Polymers to Lewis Base Stabilized Monomers

Christian Marquardt, Oliver Hegen, Ariane Vogel, Andreas Stauber, Michael Bodensteiner, Alexey Y. Timoshkin and Manfred Scheer

Chemistry A European J, 2018, 24, 360
DOI: 10.1002/chem.201705510

Structure and Bonding of a Zwitterionic Iridium Complex Supported by a Phosphine with the Parent Carba-closo-dodecaborate CB11H11– Ligand Substituent

Ahmad El-Hellani, Christos E. Kefalidis, Fook S. Tham, Laurent Maron and Vincent Lavallo

Organometallics, 2013, 32, 6887
DOI: 10.1021/om401001p

Iron‐Catalyzed Dehydropolymerization: A Convenient Route to Poly(phosphinoboranes) with Molecular‐Weight Control

André Schäfer, Titel Jurca, Joshua Turner, James R. Vance, Kajin Lee, Van An Du, Mairi F. Haddow, George R. Whittell and Ian Manners

Angewandte Chemie, 2015, 127, 4918
DOI: 10.1002/ange.201411957

B‐P Coupling: Metal Stabilized Phosphinoborate Complexes

Sourav Gayen, Sampad Shyamal, Stutee Mohapatra, P. K. Sudhadevi Antharjanam and Sundargopal Ghosh

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202302362

An investigation of polyphosphinoboranes as flame-retardant materials

Alastair W. Knights, Mitchell A. Nascimento and Ian Manners

Polymer, 2022, 247, 124795
DOI: 10.1016/j.polymer.2022.124795

Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

Heather C. Johnson, Erin M. Leitao, George R. Whittell, Ian Manners, Guy C. Lloyd-Jones and Andrew S. Weller

J. Am. Chem. Soc., 2014, 136, 9078
DOI: 10.1021/ja503335g

Cross-dehydrocoupling: A Novel Synthetic Route to P–B–P–B Chains

Souvik Pandey, Peter Lönnecke and Evamarie Hey-Hawkins

Inorg. Chem., 2014, 53, 8242
DOI: 10.1021/ic500316w

Metal‐Free Addition/Head‐to‐Tail Polymerization of Transient Phosphinoboranes, RPH‐BH2: A Route to Poly(alkylphosphinoboranes)

Christian Marquardt, Titel Jurca, Karl‐Christian Schwan, Andreas Stauber, Alexander V. Virovets, George R. Whittell, Ian Manners and Manfred Scheer

Angew Chem Int Ed, 2015, 54, 13782
DOI: 10.1002/anie.201507084

Selective Dehydrocoupling of Phosphines by Lithium Chloride Carbenoids

Sebastian Molitor, Julia Becker and Viktoria H. Gessner

J. Am. Chem. Soc., 2014, 136, 15517
DOI: 10.1021/ja509381w

Recent advances in transition metal catalysed dehydropolymerisation of amine boranes and phosphine boranes

Delong Han, Felix Anke, Michael Trose and Torsten Beweries

Coordination Chemistry Reviews, 2019, 380, 260
DOI: 10.1016/j.ccr.2018.09.016

Phosphorus–Boron‐Based Polymers Obtained by Dehydrocoupling of Ferrocenylphosphine–Borane Adducts

Souvik Pandey, Peter Lönnecke and Evamarie Hey‐Hawkins

Eur J Inorg Chem, 2014, 2014, 2456
DOI: 10.1002/ejic.201402021

Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine–Boranes

Thomas N. Hooper, Miguel A. Huertos, Titel Jurca, Sebastian D. Pike, Andrew S. Weller and Ian Manners

Inorg. Chem., 2014, 53, 3716
DOI: 10.1021/ic500032f

Paramagnetic Titanium(III) and Zirconium(III) Metallocene Complexes as Precatalysts for the Dehydrocoupling/Dehydrogenation of Amine–Boranes

Holger Helten, Barnali Dutta, James R. Vance, Matthew E. Sloan, Mairi F. Haddow, Stephen Sproules, David Collison, George R. Whittell, Guy C. Lloyd‐Jones and Ian Manners

Angewandte Chemie, 2013, 125, 455
DOI: 10.1002/ange.201207903

Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

Erin M. Leitao, Titel Jurca and Ian Manners

Nature Chem, 2013, 5, 817
DOI: 10.1038/nchem.1749