Issue 91, 2021

Redox-induced reversible P–P coupling in a uranium complex

Abstract

A synthesized redox-active multidentate N–P ligand reacted with UCl4 in the presence of KHMDS or nBuLi, where two novel U(IV) complexes with or without P–P coupling were formed, respectively. The reversible P–P coupling in these complexes was observed in redox-induced reactions.

Graphical abstract: Redox-induced reversible P–P coupling in a uranium complex

Supplementary files

Article information

Article type
Communication
Submitted
26 ago 2021
Accepted
26 out 2021
First published
30 out 2021

Chem. Commun., 2021,57, 12175-12178

Redox-induced reversible P–P coupling in a uranium complex

W. Fang, A. Carpentier, X. Sun, Y. Zhao, L. Maron and C. Zhu, Chem. Commun., 2021, 57, 12175 DOI: 10.1039/D1CC04765E

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