Issue 85, 2018

Plutonium chlorido nitrato complexes: ligand competition and computational metrics for assembly and bonding

Abstract

Four new [Pu(IV)Cln(NO3)6−n]2− (n = 0, 2, 3) and [Pu(VI)O2Cl3(NO3)]2− containing materials were crystallized from acidic, aqueous media and structurally characterized. The anions are assembled via hydrogen and halogen bonding motifs, which are rationalized computationally. The Pu–NO3 and –Cl bonds were probed using QTAIM and NLMO analyses and found to be polar and largely ionic.

Graphical abstract: Plutonium chlorido nitrato complexes: ligand competition and computational metrics for assembly and bonding

Supplementary files

Article information

Article type
Communication
Submitted
11 jul 2018
Accepted
13 set 2018
First published
27 set 2018

Chem. Commun., 2018,54, 12014-12017

Author version available

Plutonium chlorido nitrato complexes: ligand competition and computational metrics for assembly and bonding

R. G. Surbella, L. C. Ducati, J. Autschbach, K. L. Pellegrini, B. K. McNamara, J. M. Schwantes and C. L. Cahill, Chem. Commun., 2018, 54, 12014 DOI: 10.1039/C8CC05578E

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