Issue 82, 2016

First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

Abstract

We report the first-order hyperpolarizabilities (βHRS values) of individualized, length-sorted (700 ± 50 nm long) (6,5) SWNTs and corresponding polymer-wrapped (6,5) SWNT superstructures. These SWNT-based nanohybrids feature semiconducting polymers that wrap the SWNT surface in an exclusive left-handed helical fashion. Manipulation of the polymer electronic structures in these well-defined nanoscale objects provides a new avenue to modulate the magnitude of βHRS at long wavelength (1280 nm).

Graphical abstract: First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

Supplementary files

Article information

Article type
Communication
Submitted
28 jul 2016
Accepted
07 set 2016
First published
14 set 2016

Chem. Commun., 2016,52, 12206-12209

First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

G. Depotter, J. Olivier, M. G. Glesner, P. Deria, Y. Bai, G. Bullard, A. S. Kumbhar, M. J. Therien and K. Clays, Chem. Commun., 2016, 52, 12206 DOI: 10.1039/C6CC06190G

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