Issue 5, 2015

A divergent synthesis of 3,10-dialkylpicenes

Abstract

A series of 3,10-dialkylated picenes has been synthesized from 3,10-dimethoxypicene through a divergent approach involving Ni-catalyzed alkynylation of a C–O bond, alkylation, and hydrogenation.

Graphical abstract: A divergent synthesis of 3,10-dialkylpicenes

Supplementary files

Article information

Article type
Research Article
Submitted
31 jan 2015
Accepted
13 mar 2015
First published
16 mar 2015

Org. Chem. Front., 2015,2, 536-541

Author version available

A divergent synthesis of 3,10-dialkylpicenes

X. Chen, S. Nishinaga, Y. Okuda, J. Zhao, J. Xu, H. Mori and Y. Nishihara, Org. Chem. Front., 2015, 2, 536 DOI: 10.1039/C5QO00039D

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