Issue 3, 2009

Cyanooximes as effective and selective co-crystallizing agents

Abstract

The ability of cyanooxime-based synthons to act as versatile synthetic tools for the construction of co-crystals is demonstrated through the preparation and structural characterization of seven co-crystals. Cyanooximes can bind effectively to both five-membered and six-membered N-heterocyclic hydrogen-bond acceptors, and they also display selectivity towards the best acceptor (as determined using semi-empirical AM1 calculations) in ditopic compounds.

Graphical abstract: Cyanooximes as effective and selective co-crystallizing agents

Supplementary files

Article information

Article type
Paper
Submitted
08 jul 2008
Accepted
19 set 2008
First published
15 out 2008

CrystEngComm, 2009,11, 439-443

Cyanooximes as effective and selective co-crystallizing agents

C. B. Aakeröy, D. J. Salmon, M. M. Smith and J. Desper, CrystEngComm, 2009, 11, 439 DOI: 10.1039/B811322J

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