Fluoride-Ion Conduction in Ba4M3F17 (M = Bi3+, Y3+) with Conductive M6F13 Cage Units
Abstract
Nanoporous cage structures serve as ideal units for ionic conduction due to the weak bonds formed between the central ions and the surrounding framework, which facilitates high ion mobility. However, in the realm of inorganic compounds, research into ionic conduction within cage structures with mobile central ions has been limited primarily to the oxide-ion conductor 12CaO·7Al2O3, and the superiority of the cage structure compared with other conduction units remains unclear. This study investigates Ba4M3F17 (M = Bi3+, Y3+), which incorporate M6F13 cage units and a fluorite-type framework commonly associated with F− conduction. Bond valence energy landscape calculations suggest that F− conduction pathways in Ba4M3F17 are primarily facilitated through the M6F13 cage units rather than the fluorite-type framework. The calculated barriers for F− migration within the cage unit are extremely low, although the rigid cation-ordered fluorite-type framework may hinder fast ionic conduction in Ba4M3F17. The conductivity can be increased by modifying the cage units and quantity of F vacancies, reaching 5.8 × 10−6 S cm−1 at 200 ℃ for Ba4Bi3−xPbxF17−x (x = 0.3). This research provides valuable insights into the role of the cage structure in ionic conductors, contributing to the development of high-performance ionic conductors based on cage structures.
- This article is part of the themed collection: Journal of Materials Chemistry A HOT Papers