Issue 42, 2023

A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Abstract

A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+I) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu–S}n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.

Graphical abstract: A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Supplementary files

Article information

Article type
Communication
Submitted
06 jul 2023
Accepted
16 out 2023
First published
16 out 2023
This article is Open Access
Creative Commons BY-NC license

J. Mater. Chem. C, 2023,11, 14540-14544

A p-type semi-conducting copper(I)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

C. Andrade, S. Hawila, A. Abdallah, J. Rukemampunzi, A. Mesbah, N. Guillou, F. Perret, S. Wuttke, T. Niehaus, R. Debord, O. Boisron, S. Pailhès and A. Demessence, J. Mater. Chem. C, 2023, 11, 14540 DOI: 10.1039/D3TC02379F

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