Issue 20, 2023

Melanin/PEDOT:PSS blend as organic mixed ionic electronic conductor (OMIEC) for sustainable electronics

Abstract

Organic mixed ionic–electronic conductors (OMIECs) can efficiently couple and transport ionic and electronic charge species, making them key elements for bioelectronics, neuromorphic computing, soft robotics, and energy storage applications. Here, we have synthesized a water-soluble, bio-inspired ion conductor melanin (Mel) and blended it with benchmark conducting polymer poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) to form a new OMIEC. We explored the potential of Mel/PEDOT:PSS OMIEC blends in two critical device applications: organic electrochemical transistors (OECTs) and supercapacitors (SuperCaps). Mel incorporation into PEDOT:PSS enhances the ionic–electronic coupling when ions from an electrolyte are injected into the material, increasing the volumetric capacitance of PEDOT:PSS films ten-fold. The addition of Mel in PEDOT:PSS also increases the transconductance of OECTs (from 7 ± 1 to 11 ± 3 mS), and the energy and power densities of SuperCaps, from 0.41 ± 0.02 to 0.62 ± 0.01 W h kg−1 and from 119 ± 14 to 190 ± 6 W kg−1, respectively. This work exploits the fundamental properties, device physics, and technological potential of a new and green OMIEC, ultimately aiming the development of sustainable electronics.

Graphical abstract: Melanin/PEDOT:PSS blend as organic mixed ionic electronic conductor (OMIEC) for sustainable electronics

Supplementary files

Article information

Article type
Paper
Submitted
02 set 2023
Accepted
13 set 2023
First published
13 set 2023
This article is Open Access
Creative Commons BY-NC license

Mater. Adv., 2023,4, 4732-4743

Melanin/PEDOT:PSS blend as organic mixed ionic electronic conductor (OMIEC) for sustainable electronics

N. L. Nozella, J. V. M. Lima, R. F. de Oliveira and C. F. D. O. Graeff, Mater. Adv., 2023, 4, 4732 DOI: 10.1039/D3MA00573A

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