Issue 45, 2022

Structural design strategies for superionic sodium halide solid electrolytes

Abstract

Sodium all-solid-state batteries (ASSBs) with superionic solid electrolytes (SEs) show substantial potential for large-scale energy-storage applications. Recently, lithium halide SEs have attracted attention owing to their potential compatibility with high-voltage cathode materials and high ionic conductivity. Although sodium halide SEs are believed to exhibit good electrochemical stability, very few compounds have been reported. This study provides design principles for superionic sodium halide SEs through systematic theoretical investigations of Na3MX6 (X = Cl, Br, and I). The Na3MX6 structures depend on the types and sizes of M and X: Na3MCl6 and Na3MBr6 prefer the P[3 with combining macron]1c, P21/n and R[3 with combining macron] phases, whereas Na3MI6 prefers the C2/m phase. The Na3MI6C2/m phase is found to exhibit reasonably high ionic conductivity (∼10−4 S cm−1) and anion mixing with Br further improve Na-ion migration, leading to an even higher ionic conductivity (∼10−3 S cm−1) for Na3MBr3I3. The material design principles in this study provide fundamental guidelines for the development of superionic Na halide SEs for high-voltage Na ASSBs.

Graphical abstract: Structural design strategies for superionic sodium halide solid electrolytes

Supplementary files

Article information

Article type
Paper
Submitted
28 jun 2022
Accepted
03 nov 2022
First published
05 nov 2022

J. Mater. Chem. A, 2022,10, 24301-24309

Author version available

Structural design strategies for superionic sodium halide solid electrolytes

S. Yu, K. Kim, B. C. Wood, H. Jung and K. Y. Chung, J. Mater. Chem. A, 2022, 10, 24301 DOI: 10.1039/D2TA05158C

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