Issue 13, 2022

Hydrogen-bonded cobalt(ii)-organic framework: normal and reverse spin-crossover behaviours

Abstract

A novel hydrogen-bonded metal-organic framework (H-MOF) [Co(HL)2](DMF)1.2(H2O)2.4 (1·solv), in which L = 2,2′:6′,2′′-terpyridine-5,5"-diyl biscarboxylate, was prepared. An intermolecular single H-bond between carboxy and carboxylate sites was present in this compound. The crystal structure of 1·solv showed a 4-fold interpenetrating H-bonded diamond framework. After the desorption of the crystal solvents, 1·desolv exhibited normal and reverse spin-crossover (SCO) behaviours, providing an asymmetric thermal hysteresis loop.

Graphical abstract: Hydrogen-bonded cobalt(ii)-organic framework: normal and reverse spin-crossover behaviours

Supplementary files

Article information

Article type
Paper
Submitted
14 fev 2022
Accepted
08 mar 2022
First published
08 mar 2022
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2022,51, 5034-5040

Hydrogen-bonded cobalt(II)-organic framework: normal and reverse spin-crossover behaviours

T. Kanetomo, Z. Ni and M. Enomoto, Dalton Trans., 2022, 51, 5034 DOI: 10.1039/D2DT00453D

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