Issue 5, 2022

Amine-substituent induced highly selective and rapid “turn-on” detection of carcinogenic 1,4-dioxane from purely aqueous and vapour phase with novel post-synthetically modified d10-MOFs

Abstract

Herein, an amine decorated Cd(II) metal–organic framework (MOF) with a uninodal 6-c topology was synthesized as a suitable platform for facile post-synthetic modification (PSM). The as-synthesized parent d10-MOF (1) with free –NH2 centers, when functionalized with two different carbonyl substituents (1-naphthaldehyde and benzophenone) of varying conjugation, produces two novel luminescent MOFs (LMOFs) viz.PSM-1 and PSM-2. The judicious incorporation of carbonyl substituents into the skeleton of 1 was rationalized via ESI-MS, 1H-NMR, FT-IR and PXRD analyses. Interestingly, both PSM-1 and PSM-2 show ‘turn-on’ luminescent behaviour in the presence of 1,4-dioxane with the limit of detection (LOD) as 1.079 ppm and 2.487 ppm, respectively, with prompt response time (∼55 s & ∼58 s, respectively). The inhibition of PET is comprehended to be the prime reason for luminescence enhancement upon interaction with the targeted analyte which was further validated from DFT calculations. In continuation, the PSM-MOFs were equally responsive towards 1,4-dioxane in several complex environmental matrices and cosmetic products. Additionally, vapor phase detection of 1,4-dioxane using PSM-MOFs has also been demonstrated as an additional advantage ensuring propagation of future research endeavour.

Graphical abstract: Amine-substituent induced highly selective and rapid “turn-on” detection of carcinogenic 1,4-dioxane from purely aqueous and vapour phase with novel post-synthetically modified d10-MOFs

Supplementary files

Article information

Article type
Paper
Submitted
23 nov 2021
Accepted
05 jan 2022
First published
07 jan 2022

Dalton Trans., 2022,51, 2083-2093

Amine-substituent induced highly selective and rapid “turn-on” detection of carcinogenic 1,4-dioxane from purely aqueous and vapour phase with novel post-synthetically modified d10-MOFs

U. Mondal, S. Bej, A. Hazra, S. Mandal, T. K. Pal and P. Banerjee, Dalton Trans., 2022, 51, 2083 DOI: 10.1039/D1DT03976H

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