Issue 33, 2021

A new family of silver(i) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

Abstract

The reactions of the phosphanylborane Ph2PBH2·NMe3 (L) with Ag[FAl{OC6F10(C6F5)}3] (Ag[FAl]) and AgBF4 are studied. The first reaction allowed for the synthesis of the coordination compounds [Ag(Ph2P-BH2·NMe3)(CH3CN)][FAl] (1), [Ag(Ph2P-BH2·NMe3)2][FAl] (2) and [Ag(Ph2P-BH2·NMe3)3][FAl] (3), while the second reaction afforded the one-dimensional coordination polymer [Ag(Ph2P-BH2·NMe3)]n[BF4]n (4). Compounds 1–4 are the first reported Ag(I) complexes stabilised by phosphanylboranes.

Graphical abstract: A new family of silver(i) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

Supplementary files

Article information

Article type
Communication
Submitted
03 abr 2020
Accepted
04 mai 2020
First published
04 mai 2020

New J. Chem., 2021,45, 14916-14919

A new family of silver(I) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

M. Elsayed Moussa, C. Marquardt, O. Hegen, M. Seidl and M. Scheer, New J. Chem., 2021, 45, 14916 DOI: 10.1039/D0NJ01679A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements