Issue 87, 2020

Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

Abstract

Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

Graphical abstract: Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

Supplementary files

Article information

Article type
Communication
Submitted
23 ago 2020
Accepted
02 set 2020
First published
02 set 2020

Chem. Commun., 2020,56, 13377-13380

Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

C. J. Setter, M. B. Price, L. Conte, W. Schmitt, S. R. Batten, C. Richardson, M. R. Hill, R. Babarao and L. K. Macreadie, Chem. Commun., 2020, 56, 13377 DOI: 10.1039/D0CC05715K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements