Issue 72, 2020

Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

Abstract

A one-dimensional FeII coordination polymer (CP) has been formed which includes the redox-active ligand bis-pyridyltetrathiafulvalene (py2TTF) and a Schiff base-like N2O2 ligand. This CP is both spin crossover (SCO) and redox-active in the solid-state, and chemical oxidation results in SCO modification.

Graphical abstract: Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

Supplementary files

Article information

Article type
Communication
Submitted
29 mai 2020
Accepted
31 jul 2020
First published
07 ago 2020

Chem. Commun., 2020,56, 10469-10472

Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

L. Zappe, S. Schönfeld, G. Hörner, K. A. Zenere, C. F. Leong, C. J. Kepert, D. M. D'Alessandro, B. Weber and S. M. Neville, Chem. Commun., 2020, 56, 10469 DOI: 10.1039/D0CC03788E

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