Issue 7, 2019

Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

Abstract

A bridging (μ2) neutral zwitterionic amidoxime binding mode previously unobserved between amidoximes and uranyl is reported and compared to other uranyl amidoxime complexes. Density functional theory computations show the dinuclear complex exhibits a shallow potential energy surface allowing for facile inclusion of a nonbonding water molecule in the solid-state.

Graphical abstract: Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

Supplementary files

Article information

Article type
Research Article
Submitted
19 fev 2019
Accepted
07 mar 2019
First published
12 mar 2019

Org. Chem. Front., 2019,6, 1038-1043

Author version available

Structural and computational characterization of a bridging zwitterionic-amidoxime uranyl complex

D. A. Decato and O. B. Berryman, Org. Chem. Front., 2019, 6, 1038 DOI: 10.1039/C9QO00267G

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