Issue 20, 2019

Room temperature phosphorescent triarylborane functionalized iridium complexes

Abstract

We report a series of room temperature phosphorescent compounds 1–6 composed of triarylborane (TAB) and cyclometallated iridium complexes. The optical characteristics such as energy of transition and luminescence quantum yield of these compounds can be conveniently fine-tuned by judiciously varying the cyclometallating ligand and the spacer between boron and iridium centers. Compounds 1–6 exhibit bright phosphorescence with the emission color ranging from green to red under a N2 atmosphere. A maximum quantum yield of 0.95 was observed for complex 2. Complexes 1–6 exhibit a rare type of dual emission from singlet and triplet excited states under ambient conditions. The experimental observations are well supported by the theoretical calculations.

Graphical abstract: Room temperature phosphorescent triarylborane functionalized iridium complexes

Supplementary files

Article information

Article type
Paper
Submitted
08 fev 2019
Accepted
28 mar 2019
First published
29 mar 2019

Dalton Trans., 2019,48, 6817-6823

Room temperature phosphorescent triarylborane functionalized iridium complexes

G. R. Kumar, S. K. Behera and P. Thilagar, Dalton Trans., 2019, 48, 6817 DOI: 10.1039/C9DT00590K

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