Issue 8, 2018

Imaging large amplitude out-of-plane motion in photoexcited pentafluorobenzene using time-resolved photoelectron spectroscopy: a computational study

Abstract

Excited-state dynamics of pentafluorobenzene is studied in detail for a quartic vibronic coupling model including the six b1 vibrational modes of the molecule and the two lowest excited electronic states. The study analyzes the influence of the large-amplitude out-of-plane vibrational motion on the electronic dynamics and extends to the simulation of the emerging time-resolved photoelectron spectra. The mapping of coherent non-separable electron-nuclear motion into oscillatory photoelectron signals is discussed.

Graphical abstract: Imaging large amplitude out-of-plane motion in photoexcited pentafluorobenzene using time-resolved photoelectron spectroscopy: a computational study

Article information

Article type
Paper
Submitted
31 jan 2018
Accepted
29 jun 2018
First published
04 jul 2018

Photochem. Photobiol. Sci., 2018,17, 1036-1048

Imaging large amplitude out-of-plane motion in photoexcited pentafluorobenzene using time-resolved photoelectron spectroscopy: a computational study

M. Sala and D. Egorova, Photochem. Photobiol. Sci., 2018, 17, 1036 DOI: 10.1039/C8PP00051D

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