Issue 28, 2018

Enhanced oxygen storage capacity of cation-ordered cerium–zirconium oxide induced by titanium substitution

Abstract

Herein, we report on the synthesis of Ce0.5Zr0.5−xTixO2 oxygen storage materials prepared via a solution combustion method. Ce0.5Zr0.4Ti0.1O2 showed an outstanding oxygen storage capacity (1310 μmol-O per g) at 200 °C compared to conventional κ-Ce2Zr2O8 (650 μmol-O per g) due to its cation ordering and the formation of weakly bound oxygen atoms induced by Ti substitution.

Graphical abstract: Enhanced oxygen storage capacity of cation-ordered cerium–zirconium oxide induced by titanium substitution

Supplementary files

Article information

Article type
Communication
Submitted
14 fev 2018
Accepted
15 mar 2018
First published
15 mar 2018
This article is Open Access
Creative Commons BY license

Chem. Commun., 2018,54, 3528-3531

Enhanced oxygen storage capacity of cation-ordered cerium–zirconium oxide induced by titanium substitution

Y. Goto, A. Morikawa, M. Iwasaki, M. Miura and T. Tanabe, Chem. Commun., 2018, 54, 3528 DOI: 10.1039/C8CC01308J

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