Issue 1, 2015

Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics

Abstract

We report on reversible, light-induced transformations in (CH3NH3)Pb(BrxI1−x)3. Photoluminescence (PL) spectra of these perovskites develop a new, red-shifted peak at 1.68 eV that grows in intensity under constant, 1-sun illumination in less than a minute. This is accompanied by an increase in sub-bandgap absorption at ∼1.7 eV, indicating the formation of luminescent trap states. Light soaking causes a splitting of X-ray diffraction (XRD) peaks, suggesting segregation into two crystalline phases. Surprisingly, these photo-induced changes are fully reversible; the XRD patterns and the PL and absorption spectra revert to their initial states after the materials are left for a few minutes in the dark. We speculate that photoexcitation may cause halide segregation into iodide-rich minority and bromide-enriched majority domains, the former acting as a recombination center trap. This instability may limit achievable voltages from some mixed-halide perovskite solar cells and could have implications for the photostability of halide perovskites used in optoelectronics.

Graphical abstract: Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics

Supplementary files

Article information

Article type
Edge Article
Submitted
13 out 2014
Accepted
04 nov 2014
First published
04 nov 2014
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2015,6, 613-617

Author version available

Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics

E. T. Hoke, D. J. Slotcavage, E. R. Dohner, A. R. Bowring, H. I. Karunadasa and M. D. McGehee, Chem. Sci., 2015, 6, 613 DOI: 10.1039/C4SC03141E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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