Issue 35, 2015

A silver-initiated free-radical intermolecular hydrophosphinylation of unactivated alkenes

Abstract

A scalable, operationally easy intermolecular hydrophosphinylation of various unactivated alkenes with H–P(O) compounds via an Ag(I)-initiated free radical process was developed. Mechanistic studies including electron-spin-resonance (ESR) and radical clock experiments suggest that atom transfer processes were involved in this system.

Graphical abstract: A silver-initiated free-radical intermolecular hydrophosphinylation of unactivated alkenes

Supplementary files

Article information

Article type
Communication
Submitted
11 mar 2015
Accepted
13 mar 2015
First published
13 mar 2015

RSC Adv., 2015,5, 27853-27856

A silver-initiated free-radical intermolecular hydrophosphinylation of unactivated alkenes

Z. Li, F. Fan, Z. Zhang, Y. Xiao, D. Liu and Z. Liu, RSC Adv., 2015, 5, 27853 DOI: 10.1039/C5RA04136H

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