Issue 3, 2015

Rapid mechanochemical synthesis of two new Cd(ii)-based metal–organic frameworks with high removal efficiency of Congo red

Abstract

Two new three-dimensional porous Cd(II)-based metal–organic frameworks, [Cd2(oba)2(4-bpdb)2]n·(DMF)x (TMU-8) and [Cd(oba)(4,4′-bipy)]n·(DMF)y (TMU-9), have been synthesized via mechanosynthesis by using nonlinear dicarboxylate and linear N-donor ligands and then characterized by single-crystal X-ray crystallography. The effect of using different N-donor ligands 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene (4-bpdb) and 4,4′-bipyridine (4,4′-bipy) as pillars on the final structure has been studied. Also, the removal efficiency and order reaction kinetics of these MOFs in the presence of Congo red were investigated.

Graphical abstract: Rapid mechanochemical synthesis of two new Cd(ii)-based metal–organic frameworks with high removal efficiency of Congo red

Supplementary files

Article information

Article type
Paper
Submitted
29 ago 2014
Accepted
22 out 2014
First published
22 out 2014

CrystEngComm, 2015,17, 686-692

Rapid mechanochemical synthesis of two new Cd(II)-based metal–organic frameworks with high removal efficiency of Congo red

M. Y. Masoomi, A. Morsali and P. C. Junk, CrystEngComm, 2015, 17, 686 DOI: 10.1039/C4CE01783H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements