Issue 2, 2011
From the journal:

Chemical Communications

Diameter-dependent, progressive alkylcarboxylation of single-walled carbon nanotubes†

Shunliu Deng,ab   Alexandra H. Brozena,a   Yin Zhang,ac   Yanmei Piaoa  and  YuHuang Wang*ad  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, USA
E-mail: yhw@umd.edu
Fax: +1-301-314-9121
Tel: +1-301-405-3368

b Department of Chemistry, Xiamen University, Xiamen, China

c Department of Physics, Xi'an JiaoTong University, Xi'an, China

d Maryland NanoCenter, University of Maryland, College Park, USA

Abstract

We demonstrate diameter-dependent, progressive alkylcarboxylation of single-walled carbon nanotubes by recycling a modified Billups–Birch reaction. The strong diameter dependence was confirmed by Raman spectroscopy. Alkylcarboxylation made SWNTs soluble in water, allowing the more readily functionalized, smaller diameter nanotubes to be enriched by water extraction.

Graphical abstract: Diameter-dependent, progressive alkylcarboxylation of single-walled carbon nanotubes

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C0CC03896B
Article type
Communication
Submitted
15 set 2010
Accepted
21 out 2010
First published
11 nov 2010

Chem. Commun., 2011,47, 758-760

Permissions

Request permissions

Diameter-dependent, progressive alkylcarboxylation of single-walled carbon nanotubes

S. Deng, A. H. Brozena, Y. Zhang, Y. Piao and Y. Wang, Chem. Commun., 2011, 47, 758 DOI: 10.1039/C0CC03896B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements