Issue 48, 2010

Microwave assisted covalent functionalization of C60@SWCNT peapods

Abstract

The covalent functionalization of the external wall of C60@SWCNT peapods, by in situ generated aryl diazonium salts, assisted by microwave irradiation is reported. Spectroscopic, thermal and microscopy characterization was performed. Electrochemistry revealed the three reversible reductions of encapsulated C60, however, shifted towards positive potentials when compared with those of intact C60.

Graphical abstract: Microwave assisted covalent functionalization of C60@SWCNT peapods

Supplementary files

Article information

Article type
Communication
Submitted
28 set 2010
Accepted
22 out 2010
First published
16 nov 2010

Chem. Commun., 2010,46, 9110-9112

Microwave assisted covalent functionalization of C60@SWCNT peapods

N. Karousis, S. P. Economopoulos, Y. Iizumi, T. Okazaki, Z. Liu, K. Suenaga and N. Tagmatarchis, Chem. Commun., 2010, 46, 9110 DOI: 10.1039/C0CC04108D

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