Issue 24, 2019

Assembly structures and electronic properties of truxene–porphyrin compounds studied by STM/STS

Abstract

The self-assembly of functional molecules into uniform nanostructures with innovational properties has attracted extensive research interest. In the present work, the assembly structures and electronic properties of a novel type of truxene derivative, e.g. truxene–porphyrin derivatives, were studied, for the first time, on a highly oriented pyrolytic graphite (HOPG) surface. Scanning tunneling microscopy (STM) images revealed that the truxene–porphyrin compounds could be parallelly arranged into long-ranged lamellar patterns. Density functional theory (DFT) calculations helped explain the assembly mechanisms further. Besides, order distribution of the smaller compound 1T1P in the 1,3,5-tris(10-carboxydecyloxy)-benzene (TCDB) host network was achieved, which is a reflection of the dimensional effect in the host–guest assembly. Furthermore, together with theoretical analyses, scanning tunneling spectroscopy (STS) measurements were conducted to investigate the electronic properties of truxene–porphyrin compounds. Results showed that the metalation of the porphyrin units could have a significant effect on the band gap and the position of the gap center. The study enhances our understanding of the assembly mechanism of truxene derivatives at the molecular level and paves the way towards fabricating truxene-based functional nanodevices.

Graphical abstract: Assembly structures and electronic properties of truxene–porphyrin compounds studied by STM/STS

Supplementary files

Article information

Article type
Paper
Submitted
12 mar 2019
Accepted
26 abr 2019
First published
26 abr 2019

Dalton Trans., 2019,48, 8693-8701

Assembly structures and electronic properties of truxene–porphyrin compounds studied by STM/STS

H. Xu, H. Shi, Y. Liu, J. Song, X. Lu, C. P. Gros, K. Deng and Q. Zeng, Dalton Trans., 2019, 48, 8693 DOI: 10.1039/C9DT01078E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements