Issue 73, 2018

The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Abstract

The migration of Me3Si groups (“Wanderlust”) in rare-earth triple-decker sandwich complexes of the type Ln2(COT′′)3 (COT′′ = bis(trimethylsilyl)cyclooctatetraenyl) has been elucidated by a combined experimental and computational study. For the first time, two isomers of a Ln2(COT′′)3 triple-decker have been isolated and characterized in the case of Y2(COT′′)3.

Graphical abstract: The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Supplementary files

Article information

Article type
Communication
Submitted
02 jul 2018
Accepted
20 ago 2018
First published
21 ago 2018

Chem. Commun., 2018,54, 10280-10283

The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

V. Lorenz, P. Liebing, A. Bathelier, F. Engelhardt, L. Maron, L. Hilfert, S. Busse and F. T. Edelmann, Chem. Commun., 2018, 54, 10280 DOI: 10.1039/C8CC05317K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements