Diastereoconvergence in NHC/photo dual-catalysis: stereoselective boroacylation of internal electron-poor alkenes

Xiang Zhang, Bin Zhang, Ya-Peng Wang, Mei-Ling Tang, Qian-Xi Zhang, Hao Liu, Jia-Tao Hu, Ting Qi and Jun-Long Li

Org. Biomol. Chem., 2025, 23, 9624
DOI: 10.1039/D5OB01110H

A DFT investigation of the mechanism of photoinduced radical borylation of alkyl bromides: elucidation of base-mediated photoinduced SET and SN2 processes

Nana Ma, Qiongjin Wang, Die Zhao, Bowen Duan, Shujun Li and Guisheng Zhang

Org. Chem. Front., 2025, 12, 3163
DOI: 10.1039/D5QO00048C

Hypervalent zinc(i) complexes with an NNNN-macrocycle: C–H bond activation across the zinc(i)–zinc(i) bond

Pritam Mahawar, Thayalan Rajeshkumar, Thomas P. Spaniol, Laurent Maron and Jun Okuda

Chem. Commun., 2024, 60, 11359
DOI: 10.1039/D4CC04266B

Photoinduced Reductive [4 + 2] Cycloaddition of Nitroarenes

Taiki Kaneko, Rin Ito, Toshitaka Okamura and Takaaki Sato

Org. Lett., 2025, 27, 2042
DOI: 10.1021/acs.orglett.4c04657

Usage of Organic Compounds and Nanoparticles in Everyday Life

Allah Nawaz, Muhammad Abdullah, Tahseen Anwer, Nouman Ahmed Yousaf, Rubab Sarfraz, Muhammad Talha Ahmad, Bindia, Muhammad Ali Assad, Sadaf Sajjad and Aamir Abbas

IJBR, 2025, 3, 271
DOI: 10.70749/ijbr.v3i1.506

Spin Delocalization of Nitrile-Ligated Diarylboryl Radicals Enables Photochemical Boracycle Synthesis via N-Borylimidoyl Radicals

Yubing Pang, Xiaoyu Yan, Hasil Aman, Meichen Xu and Juntao Ye

J. Am. Chem. Soc., 2025, 147, 25397
DOI: 10.1021/jacs.5c09280

Visible-Light-Mediated Radical trans-Hydroboration of Alkynes with NHC Borane

Xin Wu, Zhang Chen, Xue Peng, Zhen Wang and Yao-Fu Zeng

J. Org. Chem., 2025, 90, 658
DOI: 10.1021/acs.joc.4c02577

Borane Exchange Enables Photocatalytic Alkylation of Pyridylic C(sp3)−H Bonds with Olefins

Rui Chang, Yubing Pang and Juntao Ye

Chin. J. Chem., 2026, 44, 445
DOI: 10.1002/cjoc.70375

C(sp3)−F Bond Activation by Lewis Base‐Boryl Radicals via Concerted Electron‐Fluoride Transfer

Xueying Guo, Yuchen Zhang, Xiaoyu Lai, Yubing Pang and Xiao‐Song Xue

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202415715

Recent Advances in Methodologies for Radical‐Mechanistic Borylation†

Chang Lian, Jianning Zhang, Di Qiu and Fanyang Mo

Chin. J. Chem., 2025, 43, 104
DOI: 10.1002/cjoc.202400694

Photocatalytic Direct Borylation of Benzothiazole Heterocycles via a Triplet Activation Strategy

Ze-Le Chen, Claire Empel, Yang Xie, Rene M. Koenigs and Jun Xuan

Org. Lett., 2025, 27, 892
DOI: 10.1021/acs.orglett.4c04667

Long‐Wavelength Light‐Induced Group 13–15 Elementalization Reactions of Alkenes/Alkynes

Haruka Iimuro, Antônio Junio Araujo Dias, Ken Tanaka, Masanobu Uchiyama and Yuki Nagashima

Angew Chem Int Ed, 2026, 65
DOI: 10.1002/anie.202521882

Chemoselective Hydroheteroarylation of Alkenes via Photoredox-Neutral Proton- and BF3-Mediated Electron Transfer

Xiaoyuan Wan, Huawen Huang, Yujie Deng, Yuezhou Yuan and Guo-Jun Deng

Org. Lett., 2024, 26, 7707
DOI: 10.1021/acs.orglett.4c02825

Photocatalytic hydrogenation of alkenes using ammonia-borane

Eva Rivera-Chao, Wesley J. Olivier, Michael J. Tilby and Daniele Leonori

Chem, 2026, 12, 102711
DOI: 10.1016/j.chempr.2025.102711

Long‐Wavelength Light‐Induced Group 13–15 Elementalization Reactions of Alkenes/Alkynes

Haruka Iimuro, Antônio Junio Araujo Dias, Ken Tanaka, Masanobu Uchiyama and Yuki Nagashima

Angewandte Chemie, 2026, 138
DOI: 10.1002/ange.202521882

Photocatalytic Regioselective Hydroboration of Indoles and Benzofurans with N-Heterocyclic Carbene Boranes

Yubing Pang, Zongyang Ma and Juntao Ye

Synthesis, 2026, 58, 195
DOI: 10.1055/a-2733-4012

Hydroboration of allenes: Catalytic and non-catalytic strategies for selective functionalization

Aleksandra Szymańska, Paweł Huninik, Jakub Szyling, Shaozhong Ge and Jędrzej Walkowiak

Coordination Chemistry Reviews, 2026, 561, 217823
DOI: 10.1016/j.ccr.2026.217823

Visible-Light-Driven Borylacylation of Alkenes by NHC/Photoredox Dual Catalysis: Accessing Boryl 1,4-Dicarbonyl Architectures

Ze-Le Chen, Shu-Chao Ma, Shou-Yang Tang, Hao-Yu Yu, Yu Zhao and Jun Xuan

ACS Catal., 2025, 15, 7101
DOI: 10.1021/acscatal.5c01396

Photocatalytic Nitrile Insertion of Cyanoarenes into the C(O)–N Bond of Trifluoroacetamides: Reaction Discovery and Mechanistic Study

Bin Li, Tian Ye, Fan Zhang, Zhijuan Wang, Ji-Kang Jin, Yee Lin Phang, Xiaoguo Zhou and Feng-Lian Zhang

J. Org. Chem., 2025, 90, 15707
DOI: 10.1021/acs.joc.5c01889

Photocatalytic Boron Insertion into Thiaarenes via Boryl Radicals

Yubing Pang, Ermeng Wang and Juntao Ye

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202508379

Green-Light-Induced Cyclopropanation of Alkenes via Cooperative NHN/Ligated Boryl Radical Activation of Dichloromethane

Chang-Zhen Fang, Hong Liu, Zi-Hao Xia, Hao-Ran Kong, Yan Zhang, Qiang Liu, You-Feng Han, Zhi-Xiang Wang and Xiang-Yu Chen

Org. Lett., 2026, 28, 1893
DOI: 10.1021/acs.orglett.6c00039

C(sp3)−F Bond Activation by Lewis Base‐Boryl Radicals via Concerted Electron‐Fluoride Transfer

Xueying Guo, Yuchen Zhang, Xiaoyu Lai, Yubing Pang and Xiao‐Song Xue

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202415715

Photocatalytic Boron Insertion into Thiaarenes via Boryl Radicals

Yubing Pang, Ermeng Wang and Juntao Ye

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202508379

Development of Borylation Reactions Using N-Heterocyclic Carbene Boranes

Tsuyoshi Taniguchi

J. Synth. Org. Chem. Jpn., 2025, 83, 909
DOI: 10.5059/yukigoseikyokaishi.83.909

Advances in the Light-Promoted Transformations of N-Heterocyclic Carbene Ligated Boryl Radicals

Yang Xie and Jun Xuan

Synthesis, 2025, 57, 2551
DOI: 10.1055/a-2457-0229

Naphthalene Hydrodearomatization via Controllable Photocatalytic Hydroboration

Wengang Xu, Juan Tao, Yu-Qi Wang, Mingrui Liu, Fengyu Ma, Qiao Zhang, Feng-Lian Zhang and Mingbo Wu

J. Org. Chem., 2025, 90, 777
DOI: 10.1021/acs.joc.4c02732

Nanometal catalysts for the hydroboration of alkynes

Xianghua Zeng

Molecular Catalysis, 2025, 586, 115457
DOI: 10.1016/j.mcat.2025.115457

Photocatalytic Decyanation of Arylacetonitriles Enabled by Diphenylboryl Radicals via Spin Delocalization and α-Fragmentation

Naoki Yasukawa, Waka Okada, Koki Obata, Yuto Yoshida, Kazutake Takada and Shuichi Nakamura

ACS Catal., 2026, 16, 1738
DOI: 10.1021/acscatal.5c08437

Radical Replacement Process for Ligated Boryl Radical-Mediated Activation of Unactivated Alkyl Chlorides for C(sp3)–C(sp3) Bond Formation

Chang-Zhen Fang, Bei-Bei Zhang, Yong-Liang Tu, Qiang Liu, Zhi-Xiang Wang and Xiang-Yu Chen

J. Am. Chem. Soc., 2024, 146, 26574
DOI: 10.1021/jacs.4c10915