Antifouling polymers for nanomedicine and surfaces: recent advances

Yi Jie Eng, Tuan Minh Nguyen, He-Kuan Luo and Julian M. W. Chan

Nanoscale, 2023, 15, 15472
DOI: 10.1039/D3NR03164K

SI-PET-RAFT in flow: improved control over polymer brush growth

Andriy R. Kuzmyn, Martijn van Galen, Barend van Lagen and Han Zuilhof

Polym. Chem., 2023, 14, 3357
DOI: 10.1039/D3PY00488K

Solvent effects on surface-grafted and solution-born poly[N-(2-hydroxypropyl)methacrylamide] during surface-initiated RAFT polymerization

Yu-Min Wang, Anna Kálosi, Yuriy Halahovets, Hynek Beneš, Andres de los Santos Pereira and Ognen Pop-Georgievski

Polym. Chem., 2024, 15, 2070
DOI: 10.1039/D4PY00177J

Design, preparation, and characterization of lubricating polymer brushes for biomedical applications

Xinzhong Song, Jia Man, Yinghua Qiu, Jiali Wang, Jianing Liu, Ruijian Li, Yongqi Zhang, Jianyong Li, Jianfeng Li and Yuguo Chen

Acta Biomaterialia, 2024, 175, 76
DOI: 10.1016/j.actbio.2023.12.024

“Grafting-from” synthesis of fluorinated acrylamide polymer brushes: From controlled polymerization to outstanding antifouling properties

Diego Fernando Dorado Daza, Andres de los Santos Pereira, Ondrej Kopilec, Radoslava Sivkova, Jan Svoboda, Ondrej Sedlacek and Ognen Pop-Georgievski

Polymer, 2025, 323, 128175
DOI: 10.1016/j.polymer.2025.128175

Infection-Resistant Polypropylene Hernia Mesh: Vision & Innovations

Vipula Sethi, Chetna Verma, Amlan Gupta, Samrat Mukhopadhyay and Bhuvanesh Gupta

ACS Appl. Bio Mater., 2025, 8, 1797
DOI: 10.1021/acsabm.4c01751

Microfluidic stack reactors for the mass synthesis of polymer brushes

Markéta Vrabcová, Monika Spasovová, Volkan Cirik, Judita Anthi, Alina Pilipenco, Milan Houska, Oleksandr Romanyuk, Hana Vaisocherová-Lísalová and N. Scott Lynn

Chemical Engineering Journal, 2025, 508, 160914
DOI: 10.1016/j.cej.2025.160914

A steric hindrance-directed grafting strategy for precise functionalization of cellulose enabling high-performance triboelectric textiles

Tianmei Lyu, Chuanhui Wei, Jin He, Yuxin Ma, Yi Luo, Xiaoxuan Fan, Yiwei Ouyang, Xiao Peng and Kai Dong

Materials Science and Engineering: R: Reports, 2026, 168, 101155
DOI: 10.1016/j.mser.2025.101155

Expanding the horizons of polymer engineering: Advances in PDMS modification through RDRP techniques

Kinga Ślusarczyk, Monika Flejszar, Faustyna Stopyra and Paweł Chmielarz

European Polymer Journal, 2025, 228, 113844
DOI: 10.1016/j.eurpolymj.2025.113844

Polymer brushes based on N-methacryloxysuccinimide as platform for versatile post-polymerization modification

Radoslava Sivkova, Jan Svoboda, Jiří Pánek, Dietmar Appelhans and Ognen Pop-Georgievski

Progress in Organic Coatings, 2023, 178, 107447
DOI: 10.1016/j.porgcoat.2023.107447

Polymer Coatings for Electrochemical Biosensors

Niyaz Alizadeh, Antonios Georgas, Christos Argirusis, Georgia Sourkouni and Nikolaos Argirusis

Coatings, 2026, 16, 164
DOI: 10.3390/coatings16020164

Recent Advances in Antifouling Surface Polymer Brushes

Xin Xu, Yixin Chang, Yutong Gong, Yuhao Zhang, Ye Yu, Hui Peng and Changkui Fu

ACS Appl. Polym. Mater., 2024, 6, 1
DOI: 10.1021/acsapm.3c02150

Polymer Brushes by Grafting to Reaction in Melt: New Insights into the Mechanism

Riccardo Chiarcos, Michele Perego and Michele Laus

Macro Chemistry & Physics, 2023, 224
DOI: 10.1002/macp.202200400

Graft-then-Shrink Polymer Coatings for Localized Surface Plasmon Resonance Active Interfaces

Zengyao Qi, Katherine E. Bujold and Ryan Gavin Wylie

Langmuir, 2025, 41, 4834
DOI: 10.1021/acs.langmuir.4c04929

Tuning interfacial molecular asymmetry to engineer protective coatings with superior surface anchoring, antifouling and antibacterial properties

Yuhao Zhang, Jiawen Zhang, Qiang Yang, Yao Song, Mingfei Pan, Yajing Kan, Li Xiang, Mei Li and Hongbo Zeng

Acta Biomaterialia, 2024, 190, 107
DOI: 10.1016/j.actbio.2024.10.015

Functionalized Antifouling Polymer Brushes for Biospecific Surfaces

Erik J. Postma, Luc Scheres, Sissi de Beer, Andriy R. Kuzmyn and Han Zuilhof

Adv Materials Inter, 2025, 12
DOI: 10.1002/admi.202400955

Surface‐Grown Organic Architectures for Nanoelectronics: From Molecular Design to Device Function

Eunji Im, Jiwoo Park and Sohyun Park

Adv Funct Materials, 2025
DOI: 10.1002/adfm.202524509

Promising Solutions to Address the Non-Specific Adsorption in Biosensors Based on Coupled Electrochemical-Surface Plasmon Resonance Detection

Alina Vasilescu, Szilveszter Gáspár, Mihaela Gheorghiu, Cristina Polonschii, Roberta Maria Banciu, Sorin David, Eugen Gheorghiu and Jean-Louis Marty

Chemosensors, 2025, 13, 92
DOI: 10.3390/chemosensors13030092

Coral‐inspired anti‐biofilm therapeutic abutments as a new paradigm for prevention and treatment of peri‐implant infection

Weiran Li, Zhike Huang, Xin Li, Mengqi Zhang, Qianqian Li, Shulu Luo, Yan Li, Dingcai Wu and Shuyi Wu

SmartMat, 2024, 5
DOI: 10.1002/smm2.1284

Well‐Defined Poly(HPMAm) Brushes via Surface‐Initiated RAFT Polymerization; A Mixed‐Chain Transfer Agent (CTA) Approach

Manisha Singh, Zdeňka Sedláková, Jan Svoboda, Eliezer Jäger and Rafal Poreba

Adv Materials Inter, 2025, 12
DOI: 10.1002/admi.202500196

Catch, Release, Repeat: Reversible Protein Capture in Electric Fields Using Antifouling Polymer Brushes

Erik J. Postma, Andriy R. Kuzmyn, Karin Schroën and Sissi de Beer

Adv Materials Inter, 2026
DOI: 10.1002/admi.202501028

Threshold of Surface Initiator Concentration for Polymer Brush Growth by Surface-Initiated Atom Transfer Radical Polymerization

Tomoya Sato, Gary J. Dunderdale and Atsushi Hozumi

Langmuir, 2024, 40, 480
DOI: 10.1021/acs.langmuir.3c02756

Controlled Grafting Density of Zwitterionic Polymer Brushes for Enhanced Antifouling Properties of Polymer Particles

Ryota Niwa, Daisuke Aoki and Tatsuo Taniguchi

Langmuir, 2025, 41, 27957
DOI: 10.1021/acs.langmuir.5c03689

Magnetic-thermal dual-responsive nanoparticle emulsification and interfacial properties study and their microscopic processes in oil-water systems

Man Lv, Jinzhe Chu, Chunyue Cui, LiLi Cao, JinYan Tan and Jun Wang

Materials Today Communications, 2025, 49, 114348
DOI: 10.1016/j.mtcomm.2025.114348

Antifouling Properties of Poly(2‐Oxazoline)s and Poly(2‐Oxazine)s: Direct Comparison of Polymer‐Coated Surfaces with the Same Coating Parameters

Jan Svoboda, Niccolo Lusiani, Radoslava Sivkova, Ognen Pop‐Georgievski and Ondrej Sedlacek

Macromol. Rapid Commun., 2023, 44
DOI: 10.1002/marc.202300168

Mn-MOF catalyzed multi-site atom transfer radical polymerization electrochemical sensing of miRNA-21

Jiao Wang, Jingliang Liu, Lianzhi Li, Jinming Kong and Xueji Zhang

Microchim Acta, 2023, 190
DOI: 10.1007/s00604-023-05896-8

Preparation and properties of UiO-66 based hybrid materials via surface initiated metal-free ATRP

Meimei Yang, Yanhua Wang, Hongye Li, Peipei Bo, Bo Liu, Bo Ge, Liping Wang and Guang Li

European Polymer Journal, 2024, 202, 112612
DOI: 10.1016/j.eurpolymj.2023.112612

A green, versatile, and facile strategy for anti-biofouling surface with ultra-high graft density polyethylene glycol

Wenjie Liu, Suqin He, Hao Liu, Zeyu Shou, Kaiyuan Huo, Hongping Xiang, Aihan Feng, Wei Lu and Na Li

J Nanobiotechnol, 2024, 22
DOI: 10.1186/s12951-024-03026-x

Tunable Cell-Adhesive Surfaces by Surface-Initiated Photoinduced Electron-Transfer-Reversible Addition–Fragmentation Chain-Transfer Polymerization

Andriy R. Kuzmyn, Tanja G. Ypma and Han Zuilhof

Langmuir, 2024
DOI: 10.1021/acs.langmuir.3c02604

Fine-Tuned Functionalizable Terpolymer Brush Nanocoating Resists Protein Adsorption and Bacterial Adhesion while Promoting Macrophage Activity and Osteoblast Proliferation

Alina Pilipenco, Guruprakash Subbiahdoss, Michala Forinová, Oleksandr Romanyuk, Milan Houska, Monika Spasovová, Carmelo Covato, Andrea Scheberl, Erik Reimhult and Hana Vaisocherová-Lísalová

ACS Appl. Mater. Interfaces, 2025, 17, 65399
DOI: 10.1021/acsami.5c13698

Zwitterionic polymer brush-functionalized dual-crosslinked hydrogel via subsurface-initiated atom transfer radical polymerization for anti-fouling applications

Biwen Wang, Peng Wang, Baoluo He, Shuanhong Ma, Shujuan Liu, Qian Ye and Feng Zhou

Progress in Organic Coatings, 2023, 183, 107729
DOI: 10.1016/j.porgcoat.2023.107729

Nanopatterned Monolayers of Bioinspired, Sequence-Defined Polypeptoid Brushes for Semiconductor/Bio Interfaces

Beihang Yu, Boyce S. Chang, Whitney S. Loo, Scott Dhuey, Padraic O’Reilly, Paul D. Ashby, Michael D. Connolly, Grigory Tikhomirov, Ronald N. Zuckermann and Ricardo Ruiz

ACS Nano, 2024, 18, 7411
DOI: 10.1021/acsnano.3c10204

A comprehensive review of recent advances in nanofiltration membranes for heavy metal removal from wastewater

Zahra Samavati, Alireza Samavati, Pei Sean Goh, Ahmad Fauzi Ismail and Mohd Sohaimi Abdullah

Chemical Engineering Research and Design, 2023, 189, 530
DOI: 10.1016/j.cherd.2022.11.042

Synthetic Evolution of a Supramolecular Harpooning Mechanism to Immobilize Vesicles at Antifouling Interfaces

Jenny Englert, Lena Witzdam, Dominik Söder, Manuela Garay‐Sarmiento, Anton Joseph, Anna M. Wagner and Cesar Rodriguez‐Emmenegger

Macro Chemistry & Physics, 2023, 224
DOI: 10.1002/macp.202300306

Protein-resistant surface coatings formed by mixed polymer brushes of fluorosiloxane and zwitterion

Teng Wang, Tianqi Xu, Hao Yuan, Lang Xu, Ying Cai, Tian Zuo, Wenjing Liu, Jiawen Zhang and Lingmin Yi

Progress in Organic Coatings, 2025, 209, 109560
DOI: 10.1016/j.porgcoat.2025.109560

A Review of Recent Progress in Synthetic Polymer Surface Coatings for the Prevention of Biofilm Formation

Adrienne Shea and Matthew T. Bernards

Molecules, 2025, 30, 2710
DOI: 10.3390/molecules30132710

Temperature and pH responsive raspberry-like hollow nanoparticles prepared by seed photopolymerization under green LED irradiation

Siyuan Yu, Ying Liu, Zichang Lu, Yuanyuan Gu, Jingbao Wang, Boxuan Peng, Junxia Deng, Baoliang Liu and Jinfeng Xing

Polymer, 2025, 339, 129193
DOI: 10.1016/j.polymer.2025.129193

Long-term stability of antifouling poly(carboxybetaine acrylamide) brush coatings

Markéta Vrabcová, Monika Spasovová, Milan Houska, Kateřina Mrkvová, N. Scott Lynn, Ladislav Fekete, Oleksandr Romanyuk, Alexandr Dejneka and Hana Vaisocherová-Lísalová

Progress in Organic Coatings, 2024, 188, 108187
DOI: 10.1016/j.porgcoat.2023.108187

Probing the brush structure of end-tethered poly(oligo(ethylene glycol) methyl ether methacrylate) chains

Iryna Romanenko, Radoslava Sivkova, Jan Svoboda, Tomáš Riedel, Andres de los Santos Pereira and Ognen Pop - Georgievski

Polymer, 2025, 332, 128569
DOI: 10.1016/j.polymer.2025.128569

Antifouling Polymer Coatings for Bioactive Surfaces

He Yang, Yichen Wang, Lihua Yao, Jinghong Wang and Hong Chen

Langmuir, 2025, 41, 6471
DOI: 10.1021/acs.langmuir.4c04859

Effect of Side Groups on the Surface Parameters and Antifouling Properties of Poly(N‐Alkyl Acrylamide)‐Coated Surfaces

Ondrej Kopilec, Jan Svoboda, Radoslava Sivkova, Ondrej Sedlacek and Ognen Pop‐Georgievski

Macro Chemistry & Physics, 2025, 226
DOI: 10.1002/macp.202400481

Synthesis and self-assembly of high grafting density core-shell bottlebrush polymer with amphiphilic side chain

Jiawei Zhang, Xiaoyan Yuan, Zongquan Wu and Lixia Ren

Reactive and Functional Polymers, 2024, 202, 105997
DOI: 10.1016/j.reactfunctpolym.2024.105997

Zwitterions modified biosensors improve detection performance in complex food matrices

Chen Zhang, Huixian Huang, Xin Wang, Yiran Zhang, Wanshu Sun, Qingliang Liu, Xiuzhi Zhou, Wentao Xu, Yunbo Luo, Kunlun Huang and Nan Cheng

Trends in Food Science & Technology, 2024, 145, 104374
DOI: 10.1016/j.tifs.2024.104374