Issue 64, 2021
From the journal:

Chemical Communications

Mono-mercapto-functionalized pillar[5]arene: a host–guest complexation accelerated reversible redox dimerization†

Jianbing Jin, ORCID logo a   Jiarong Miaoa  and  Chuyang Cheng*a  

* Corresponding authors

a College of Chemistry, Sichuan University, Chengdu, China
E-mail: cycheng@scu.edu.cn

Abstract

A mono-mercapto-functionalized pillar[5]arene and its dimer, capable of being reversibly interconverted, were successfully synthesized. Fascinatingly, a faster reversible redox conversion involving a dynamic disulfide bond was observed between their host–guest complexes compared with the hosts themselves.

Graphical abstract: Mono-mercapto-functionalized pillar[5]arene: a host–guest complexation accelerated reversible redox dimerization

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Article information

DOI
https://doi.org/10.1039/D1CC03010H
Article type
Communication
Submitted
08 jun 2021
Accepted
08 jul 2021
First published
08 jul 2021

Chem. Commun., 2021,57, 7950-7953

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Mono-mercapto-functionalized pillar[5]arene: a host–guest complexation accelerated reversible redox dimerization

J. Jin, J. Miao and C. Cheng, Chem. Commun., 2021, 57, 7950 DOI: 10.1039/D1CC03010H

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