The solvent-induced isomerization of silver thiolate clusters with symmetry transformation

Xu-Ran Chen; Ling Yang; Yu-Ling Tan; Hong Yu; Chun-Yan Ni; Zheng Niu; Jian-Ping Lang

doi:10.1039/D0CC01195A

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The solvent-induced isomerization of silver thiolate clusters with symmetry transformation†

Xu-Ran Chen,^a Ling Yang,^a Yu-Ling Tan,^a Hong Yu,*^a Chun-Yan Ni,^a Zheng Niu*^a and Jian-Ping Lang

*^ab

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* Corresponding authors

^a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, People's Republic of China
E-mail: jplang@suda.edu.cn, nkniuzheng@163.com
Fax: +86-512-65880328

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, People's Republic of China

Abstract

A novel ligand-stabilized Ag12 nanocluster was synthesized as a model cluster to investigate the solvent-induced isomerization of Ag12 clusters. Another two novel Ag12 clusters as well as their related symmetry transformations were also successfully obtained through the above solvent-induced isomerization process.

This article is part of the themed collection: SU 120: Celebrating 120 Years of Soochow University

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Article information

DOI: https://doi.org/10.1039/D0CC01195A
Article type: Communication
Submitted: 14 fev 2020
Accepted: 20 fev 2020
First published: 20 fev 2020

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Chem. Commun., 2020,56, 3649-3652

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The solvent-induced isomerization of silver thiolate clusters with symmetry transformation

X. Chen, L. Yang, Y. Tan, H. Yu, C. Ni, Z. Niu and J. Lang, Chem. Commun., 2020, 56, 3649 DOI: 10.1039/D0CC01195A

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Chemical Communications

The solvent-induced isomerization of silver thiolate clusters with symmetry transformation†

Abstract

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The solvent-induced isomerization of silver thiolate clusters with symmetry transformation

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